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Water-reactive substances [1] are those that spontaneously undergo a chemical reaction with water, often noted as generating flammable gas. [2] Some are highly reducing in nature. [ 3 ] Notable examples include alkali metals , lithium through caesium , and alkaline earth metals , magnesium through barium .
Lithium oxide reacts with water and steam, forming lithium hydroxide and should be isolated from them. Its usage is also being investigated for non-destructive emission spectroscopy evaluation and degradation monitoring within thermal barrier coating systems.
Lithium reacts with water easily, but with noticeably less vigor than other alkali metals. The reaction forms hydrogen gas and lithium hydroxide. [10] When placed over a flame, lithium compounds give off a striking crimson color, but when the metal burns strongly, the flame becomes a brilliant silver.
All oxides of group 1 & 2 elements are basic (except BeO), they react with water to form a base: [2] Lithium oxide reacts with water to produce lithium hydroxide: Li 2 O + H 2 O → 2 LiOH; Sodium oxide reacts with water to produce sodium hydroxide: Na 2 O + H 2 O → 2 NaOH; Potassium oxide reacts with water to produce potassium hydroxide: K 2 ...
Alkyl-lithium compounds are stored under inert gas to prevent loss of activity and for reasons of safety. n-BuLi reacts violently with water: C 4 H 9 Li + H 2 O → C 4 H 10 + LiOH. This is an exergonic and highly exothermic reaction. If oxygen is present the butane produced may ignite. BuLi also reacts with CO 2 to give lithium pentanoate:
Lithium borohydride reacts with water to produce hydrogen. This reaction can be used for hydrogen generation. [8] Although this reaction is usually spontaneous and violent, somewhat-stable aqueous solutions of lithium borohydride can be prepared at low temperature if degassed, distilled water is used and exposure to oxygen is carefully avoided. [9]
Lithium nitride is prepared by direct reaction of elemental lithium with nitrogen gas: [2] 6 Li + N 2 → 2 Li 3 N. Instead of burning lithium metal in an atmosphere of nitrogen, a solution of lithium in liquid sodium metal can be treated with N 2. Lithium nitride must be protected from moisture as it reacts violently with water to produce ammonia:
However, lithium metal reacts violently with water and thus the aqueous design requires a solid electrolyte interface between the lithium and electrolyte. Commonly, a lithium-conducting ceramic or glass is used, but conductivity are generally low (on the order of 10 −3 S/cm at ambient temperatures). [26]