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The coagulation-flocculation process can be used as a preliminary or intermediary step between other water or wastewater treatment processes like filtration and sedimentation. Iron and aluminium salts are the most widely used coagulants but salts of other metals such as titanium and zirconium have been found to be highly effective as well. [1] [2]
Iron(III) sulfate (or ferric sulfate), is a family of inorganic compounds with the formula Fe 2 (SO 4) 3 (H 2 O) n. A variety of hydrates are known, including the most commonly encountered form of "ferric sulfate". Solutions are used in dyeing as a mordant, and as a coagulant for industrial wastes. Solutions of ferric sulfate are also used in ...
Particles finer than 0.1 μm (10 −7 m) in water remain continuously in motion due to electrostatic charge (often negative) which causes them to repel each other. [citation needed] Once their electrostatic charge is neutralized by the use of a coagulant chemical, the finer particles start to collide and agglomerate (collect together) under the influence of Van der Waals forces.
Basically, coagulation is a process of addition of coagulant to destabilize a stabilized charged particle. Meanwhile, flocculation is a technique that promotes agglomeration and assists in the settling of particles. The most common used coagulant is alum, Al 2 (SO 4) 3 ·14H 2 O. The chemical reaction involved:
Iron(II) sulfate is typically used as the iron catalyst. The exact mechanisms of the redox cycle are uncertain, and non-OH • oxidizing mechanisms of organic compounds have also been suggested. [citation needed] Therefore, it may be appropriate to broadly discuss Fenton chemistry rather than a specific Fenton reaction.
Iron(II) sulfate outside a titanium dioxide factory in Kaanaa, Pori, Finland. Upon dissolving in water, ferrous sulfates form the metal aquo complex [Fe(H 2 O) 6] 2+, which is an almost colorless, paramagnetic ion. On heating, iron(II) sulfate first loses its water of crystallization and the original green crystals are converted into a white ...
Aluminium sulfate is a salt with the formula Al 2 (SO 4) 3. It is soluble in water and is mainly used as a coagulating agent (promoting particle collision by neutralizing charge) in the purification of drinking water [ 3 ] [ 4 ] and wastewater treatment plants , and also in paper manufacturing.
One method of eutrophication remediation is the application of aluminum sulfate, a salt commonly used in the coagulation process of drinking water treatment. Aluminum sulfate, or "alum" as it is commonly referred, has been found to be an effective lake management tool by reducing the phosphorus load. [2] Sediment core sampled from a Minnesota lake.