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The heating value depends on the source of gas that is used and the process that is used to liquefy the gas. The range of heating value can span ±10 to 15 percent. A typical value of the higher heating value of LNG is approximately 50 MJ/kg or 21,500 BTU/lb. [2] A typical value of the lower heating value of LNG is 45 MJ/kg or 19,350 BTU/lb.
The boiling point corresponds to the temperature at which the vapor pressure of the liquid equals the surrounding environmental pressure. Thus, the boiling point is dependent on the pressure. Boiling points may be published with respect to the NIST, USA standard pressure of 101.325 kPa (1 atm), or the IUPAC standard pressure of 100.000 kPa (1 ...
Lee [4] developed a modified form of the Antoine equation that allows for calculating vapor pressure across the entire temperature range using the acentric factor (𝜔) of a substance. The fundamental structure of the equation is based on the van der Waals equation and builds upon the findings of Wall [ 5 ] and Gutmann et al. [ 6 ] , who ...
Values are given in terms of temperature necessary to reach the specified pressure. Valid results within the quoted ranges from most equations are included in the table for comparison. A conversion factor is included into the original first coefficients of the equations to provide the pressure in pascals (CR2: 5.006, SMI: -0.875).
LNG: 332.7 WEL: 318 Zhang et al. 310 22 Ti titanium; use: 425 LNG: 425 WEL: 425 Zhang et al. 427 23 V vanadium; use: 444 LNG: 459 WEL: 453 Zhang et al. 451 24 Cr chromium; use: 339.5 LNG: 339.5 WEL: 339 Zhang et al. 347 25 Mn manganese; use: 221 LNG: 221 WEL: 220 Zhang et al. 225 26 Fe iron; use: 340 LNG: 340 WEL: 347 Zhang et al. 354 27 Co ...
Boiling point (°C) K b (°C⋅kg/mol) Freezing point (°C) K f (°C⋅kg/mol) Data source; Aniline: 184.3 3.69 –5.96 –5.87 K b & K f [1] Lauric acid: 298.9 44 –3.9 Acetic acid: 1.04 117.9 3.14 16.6 –3.90 K b [1] K f [2] Acetone: 0.78 56.2 1.67 –94.8 K b [3] Benzene: 0.87 80.1 2.65 5.5 –5.12 K b & K f [2] Bromobenzene: 1.49 156.0 6. ...
At ambient pressure the boiling point of liquefied helium is 4.22 K (−268.93 °C). Below 2.17 K liquid 4 He becomes a superfluid (Nobel Prize 1978, Pyotr Kapitsa) and shows characteristic properties such as heat conduction through second sound, zero viscosity and the fountain effect among others.
If a sufficient amount of liquid is vaporized within a closed container, it produces pressures that can rupture the pressure vessel. Hence the use of pressure relief valves and vent valves are important. [2] The expansion ratio of liquefied and cryogenic from the boiling point to ambient is: nitrogen – 1 to 696; liquid helium – 1 to 745 ...