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Adams' catalyst, also known as platinum dioxide, is usually represented as platinum(IV) oxide hydrate, PtO 2 •H 2 O. It is a catalyst for hydrogenation and hydrogenolysis in organic synthesis . [ 1 ]
Ammonium hexachloroplatinate is used in platinum plating. Heating (NH 4) 2 [PtCl 6] under a stream of hydrogen at 200 °C produces platinum sponge. Treating this with chlorine gives H 2 [PtCl 6]. [2] Ammonium hexachloroplatinate decomposes to yield platinum sponge when heated to high temperatures: [2] [5] 3(NH 4) 2 PtCl 6 → 3Pt(s) + 2NH 4 Cl ...
Ammonium cerium(IV) nitrate – [NH 4] 2 [Ce(NO 3) 6] Ammonium cerium(IV) sulfate – [NH 4] 4 [Ce(SO 4) 4] Ammonium chloride – [NH 4]Cl [39] Ammonium chlorate – [NH 4]ClO 3 [40] Ammonium cyanide – [NH 4]CN [41] Ammonium dichromate – [NH 4] 2 Cr 2 O 7 [42] Ammonium dihydrogen phosphate – [NH 4]H 2 PO 4; Ammonium hexafluoroaluminate ...
Pages in category "Platinum(IV) compounds" The following 14 pages are in this category, out of 14 total. This list may not reflect recent changes. A. Adams' catalyst;
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Sodium hexachloroplatinate(IV), the sodium salt of chloroplatinic acid, is an inorganic compound with the formula Na 2 [PtCl 6], consisting of the sodium cation and the hexachloroplatinate anion. As explained by Cox and Peters, anhydrous sodium hexachloroplatinate, which is yellow, tends to form the orange hexahydrate upon storage in humid air.
Chloroplatinic acid (also known as hexachloroplatinic acid) is an inorganic compound with the formula [H 3 O] 2 [PtCl 6](H 2 O) x (0 ≤ x ≤ 6). A red solid, it is an important commercial source of platinum, usually as an aqueous solution.
When heated to 150–180 °C, it decomposes with autooxidation to plutonium (VI) with the formation of plutonyl nitrate (PuO 2 (NO 3) 2).Upon evaporation of concentrated nitric acid solutions of plutonium nitrate and alkali metal nitrates, double nitrates of the composition Me 2 [Pu(NO 3) 6] are formed, where Me = Cs +, Rb +, K +, Tl +, NH 4 +, analogous to ceric ammonium nitrate.