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On the other hand, THF deaggregates hexameric butyl lithium: the tetramer is the main species, and ΔG for interconversion between tetramer and dimer is around 11 kcal/mol. [21] TMEDA can also chelate to the lithium cations in n-butyllithium and form solvated dimers such as [(TMEDA) LiBu-n)] 2.
2-Methylpentane, trivially known as isohexane, is a branched-chain alkane with the molecular formula C 6 H 14. It is a structural isomer of hexane composed of a methyl group bonded to the second carbon atom in a pentane chain.
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
2,2,4,4-Tetramethyl-3-t-butyl-pentane-3-ol or tri-tert-butylcarbinol is an organic compound with formula C 13 H 28 O, ((H 3 C) 3 C) 3 COH, or t Bu 3 COH. [1]It is an alcohol that can be viewed as a structural analog of a tridecane isomer (2,2,4,4-tetramethyl-3-t-butylpentane) where the central hydrogen has been replaced by a hydroxyl group -OH.
When necessary, the position of the hydroxyl group is indicated by a number between the alkane name and the -ol: propan-1-ol for CH 3 CH 2 CH 2 OH, propan-2-ol for CH 3 CH(OH)CH 3. If a higher priority group is present (such as an aldehyde , ketone , or carboxylic acid ), then the prefix hydroxy- is used, [ 19 ] e.g., as in 1-hydroxy-2 ...
A cycloalkyl group is derived from a cycloalkane by removal of a hydrogen atom from a ring and has the general formula −C n H 2n−1. [2] Typically an alkyl is a part of a larger molecule. In structural formulae , the symbol R is used to designate a generic (unspecified) alkyl group.
3-Methylpentane is a branched alkane with the molecular formula C 6 H 14. It is a structural isomer of hexane composed of a methyl group bonded to the third carbon atom in a pentane chain. It is of similar structure to the isomeric 2-methylpentane , which has the methyl group located on the second carbon of the pentane chain.
Pentyl is a five-carbon alkyl group or substituent with chemical formula-C 5 H 11.It is the substituent form of the alkane pentane.. In older literature, the common non-systematic name amyl was often used for the pentyl group.