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Atom transfer radical polymerization (ATRP) is an example of a reversible-deactivation radical polymerization. Like its counterpart, ATRA, or atom transfer radical addition, ATRP is a means of forming a carbon-carbon bond with a transition metal catalyst. Polymerization from this method is called atom transfer radical addition polymerization (ATRAP
Living free radical polymerization is a type of living polymerization where the active polymer chain end is a free radical.Several methods exist. IUPAC recommends [1] to use the term "reversible-deactivation radical polymerization" instead of "living free radical polymerization", though the two terms are not synonymous.
ATRP may refer to: GTRI Agricultural Technology Research Program; Atom transfer radical polymerization; Avios Travel Rewards Programme This page was last edited on ...
Atom transfer radical polymerization (ATRP): based on the formation of a carbon-carbon bond by atom transfer radical addition. This method, independently discovered in 1995 by Mitsuo Sawamoto [ 16 ] and by Jin-Shan Wang and Krzysztof Matyjaszewski , [ 17 ] [ 18 ] requires reversible activation of a dormant species (such as an alkyl halide ) and ...
Although copper complexes (in combination with relevant ligands) have long been used as catalysts for organic reactions such as atom transfer radical addition (ATRA) and copper(I)-catalyzed alkyne-azide cycloaddition (CuAAC), copper complex catalyzed RDRP was not reported until 1995 when Jin-Shan Wang and Krzysztof Matyjaszewski introduced it as atom transfer radical polymerization (ATRP).
Krzysztof "Kris" Matyjaszewski (Polish: [ˈkʂɨʂtɔf matɨjaˈʂɛfskʲi]; born April 8, 1950) is a Polish-American [1] chemist.He is the J.C. Warner Professor of the Natural Sciences at the Carnegie Mellon University [2] Matyjaszewski is best known for the discovery of atom transfer radical polymerization (ATRP), a novel method of polymer synthesis that has revolutionized the way ...
There is a mode of polymerization referred to as reversible-deactivation polymerization which is distinct from living polymerization, despite some common features. Living polymerization requires a complete absence of termination reactions, whereas reversible-deactivation polymerization may contain a similar fraction of termination as conventional polymerization with the same concentration of ...
In 1995, Sawamoto [2] and Krzysztof Matyjaszewski [3] described Atom-transfer radical-polymerization (ATRP) almost simultaneously and independently. Until 2008, Sawamoto published more than 350 original works and more than 30 systematic reviews.