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Recrystallization kinetics are commonly observed to follow the profile shown. There is an initial 'nucleation period' t 0 where the nuclei form, and then begin to grow at a constant rate consuming the deformed matrix. Although the process does not strictly follow classical nucleation theory it is often found that such mathematical descriptions ...
The Avrami equation describes how solids transform from one phase to another at constant temperature. It can specifically describe the kinetics of crystallisation , can be applied generally to other changes of phase in materials, like chemical reaction rates, and can even be meaningful in analyses of ecological systems.
Grain growth has long been studied primarily by the examination of sectioned, polished and etched samples under the optical microscope.Although such methods enabled the collection of a great deal of empirical evidence, particularly with regard to factors such as temperature or composition, the lack of crystallographic information limited the development of an understanding of the fundamental ...
The methods used to determine the degree of crystallinity can be incorporated over time to measure the kinetics of crystallization. The most basic model for polymer crystallization kinetics comes from Hoffman nucleation theory. The crystallization process of polymers does not always obey simple chemical rate equations. Polymers can crystallize ...
Recrystallization is a method used to purify chemicals by dissolving a mixture of a compound and its impurities, in an appropriate solvent, prior to heating the solution. [1] Following the dissolution of crude product, the mixture will passively cool, yielding a crystallized compound and its impurities as separate entities.
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Dynamic recrystallization (DRX) is a type of recrystallization process, found within the fields of metallurgy and geology. In dynamic recrystallization, as opposed to static recrystallization, the nucleation and growth of new grains occurs during deformation rather than afterwards as part of a separate heat treatment.
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