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In condensed matter physics and inorganic chemistry, the cation-anion radius ratio can be used to predict the crystal structure of an ionic compound based on the relative size of its atoms. It is defined as the ratio of the ionic radius of the positively charged cation to the ionic radius of the negatively charged anion in a cation-anion ...
An octahedron may then form with a radius ratio greater than or equal to 0.414, but as the ratio rises above 0.732, a cubic geometry becomes more stable. This explains why Na + in NaCl with a radius ratio of 0.55 has octahedral coordination, whereas Cs + in CsCl with a radius ratio of 0.93 has cubic coordination. [5]
r B is the radius of the B cation. r O is the radius of the anion (usually oxygen). In an ideal cubic perovskite structure, the lattice parameter (i.e., length) of the unit cell (a) can be calculated using the following equation: [ 1 ]
Ionic radius, r ion, is the radius of a monatomic ion in an ionic crystal structure. Although neither atoms nor ions have sharp boundaries, they are treated as if they were hard spheres with radii such that the sum of ionic radii of the cation and anion gives the distance between the ions in a crystal lattice .
For all these radius ratios a compact packing is known that achieves the maximum possible packing fraction (above that of uniformly-sized discs) for mixtures of discs with that radius ratio. [9] All nine have ratio-specific packings denser than the uniform hexagonal packing, as do some radius ratios without compact packings. [10]
The Bohr radius ( ) is a physical constant, approximately equal to the most probable distance between the nucleus and the electron in a hydrogen atom in its ground state. It is named after Niels Bohr , due to its role in the Bohr model of an atom.
The golden ratio φ and its negative reciprocal −φ −1 are the two roots of the quadratic polynomial x 2 − x − 1. The golden ratio's negative −φ and reciprocal φ −1 are the two roots of the quadratic polynomial x 2 + x − 1. The golden ratio is also an algebraic number and even an algebraic integer.
The formula is based on experimental results by J. B. Johnson from around 1900 as an alternative to Euler's critical load formula under low slenderness ratio (the ratio of radius of gyration to effective length) conditions.