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The stoichiometric ratio is 34.2% aluminum and 65.8% perchlorate by mass. A ratio of seven parts potassium perchlorate to three parts dark pyro aluminium is the composition used by most pyrotechnicians. For best results, the aluminium powder should be "Dark Pyro" grade, with a flake particle shape, and a particle size of fewer than 10 micrometres.
Flake particles easier to ignite and better for pyrotechnics than spherical ones. In presence of moisture reacts with potassium chlorate and perchlorate, yielding hydrogen. Particle size selected according to the required burn rate. [1] Magnesium – more sensitive and violent than aluminium, increases probability of spontaneous ignition in ...
Potassium alum, potash alum, or potassium aluminium sulfate is a chemical compound first mentioned under various Sanskrit names in Ayurvedic medicinal texts such as charak samhita, sushrut samhita, and ashtang hridaya; is chemically defined as the double sulfate of potassium and aluminium, with chemical formula KAl(SO 4) 2.
Aluminium arsenate – AlAsO 4 [6] Aluminium arsenide – AlAs [7] [8] Aluminium diboride – AlB 2 [9] [10] Aluminium bromide – AlBr 3 [11] Aluminium carbide – Al 4 C 3 [12] Aluminium iodide – AlI 3 [13] Aluminium nitride – AlN [14] Aluminium oxide – Al 2 O 3 [15] Aluminium phosphide – AlP [16] Aluminium chloride – AlCl 3 [17 ...
aluminium sulfate: 10043–01–3 Al 2 S 3: aluminium sulfide: 1302–81–4 ... potassium perchlorate: 7778–74–7 K 2 CuCl 4: potassium tetrachlorocuprate: 13877 ...
Perchlorate concentration was the highest in Chilean nitrate, ranging from 3.3 to 3.98%. [51] Perchlorate in the solid fertilizer ranged from 0.7 to 2.0 mg g −1, variation of less than a factor of 3 and it is estimated that sodium nitrate fertilizers derived from Chilean caliche contain approximately 0.5–2 mg g −1 of perchlorate anion. [74]
Potassium perchlorate in crystal form. Potassium perchlorate is prepared industrially by treating an aqueous solution of sodium perchlorate with potassium chloride.This single precipitation reaction exploits the low solubility of KClO 4, which is about 1/100 as much as the solubility of NaClO 4 (209.6 g/100 mL at 25 °C).
Other rarely used oxidizers are ammonium and potassium perchlorate. Two main issues need to be addressed with respect to the oxidizer if one is using potassium nitrate. The most important issue is the purity of the material. If a purchased material does not perform satisfactorily it may be necessary to recrystallize the KNO 3. The second ...
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