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The compound is prepared by base-catalyzed condensation of 1-hydroxyhexane-2,5-dione, a derivative of hydroxymethylfurfural. [2] The structure has been confirmed by X-ray crystallography. [2] Quantum calculations also indicate that the enol is strongly favored relative to the diketo tautomer.
2-Pentanone or methyl propyl ketone (MPK) is a ketone and solvent of minor importance. It is comparable to methyl ethyl ketone , but has a lower solvency and is more expensive. [ 5 ] It occurs naturally in Nicotiana tabacum (Tobacco) [ 6 ] and blue cheese as a metabolic product of Penicillium mold growth.
Hydroxyacetone, also known as acetol, is the organic chemical with the formula CH 3 C(O)CH 2 OH. It consists of a primary alcohol substituent on acetone. It is an α-hydroxyketone, also called a ketol, and is the simplest hydroxy ketone structure. It is a colorless, distillable liquid.
2-Methyl-2,4-pentanediol (MPD) is an organic compound with the formula (CH 3) 2 C(OH)CH 2 CH(OH)CH 3. This colourless liquid is a chiral diol . It is produced industrially from diacetone alcohol by hydrogenation . [ 4 ]
In the laboratory, this compound may be prepared by treating sodium cyanide with acetone, followed by acidification: [3]. Considering the high toxicity of acetone cyanohydrin, a lab scale production has been developed using a microreactor-scale flow chemistry [4] to avoid needing to manufacture and store large quantities of the reagent.
2-Cyclopentenone is the organic compound with the chemical formula (CH 2) 2 (CH) 2 CO. 2-Cyclopentenone contains two functional groups, a ketone and an alkene. It is a colorless liquid. Its isomer, 3-cyclopentenone is less commonly encountered.
Diacetone alcohol is an organic compound with the formula CH 3 C(O)CH 2 C(OH)(CH 3) 2, sometimes called DAA. This colorless liquid is a common synthetic intermediate used for the preparation of other compounds, and is also used as a solvent.
Safety data sheet (SDS) MSDS at Sigma Aldrich Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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