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Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity. [1]
The electronic properties of graphene are significantly influenced by the supporting substrate. [59] [60] The Si(100)/H surface does not perturb graphene's electronic properties, whereas the interaction between it and the clean Si(100) surface changes its electronic states significantly. This effect results from the covalent bonding between C ...
Graphene is the only form of carbon (or solid material) in which every atom is available for chemical reaction from two sides (due to the 2D structure). Atoms at the edges of a graphene sheet have special chemical reactivity. Graphene has the highest ratio of edge atoms of any allotrope. Defects within a sheet increase its chemical reactivity ...
Typical examples include graphene, topological insulators, bismuth antimony thin films and some other novel nanomaterials, [1] [4] [5] in which the electronic energy and momentum have a linear dispersion relation such that the electronic band structure near the Fermi level takes the shape of an upper conical surface for the electrons and a ...
It is possible to tune these nanomechanical properties with further chemical doping to change the bonding environment at the edge of graphene nanoribbons. [33] While increasing the width of graphene nanoribbons, the mechanical properties will converge to the value measured on the graphene sheets.
The sensitivity of graphene chemical gas sensors can be dramatically enhanced by functionalization, for example, coating the film with a thin layer of certain polymers. The thin polymer layer acts like a concentrator that absorbs gaseous molecules. The molecule absorption introduces a local change in electrical resistance of graphene sensors ...
A two-dimensional semiconductor (also known as 2D semiconductor) is a type of natural semiconductor with thicknesses on the atomic scale. Geim and Novoselov et al. initiated the field in 2004 when they reported a new semiconducting material graphene, a flat monolayer of carbon atoms arranged in a 2D honeycomb lattice. [1]
Partial hydrogenation results in hydrogenated graphene, which was reported by Elias et al. in 2009 by a TEM study to be "direct evidence for a new graphene-based derivative". The authors viewed the panorama as "a whole range of new two-dimensional crystals with designed electronic and other properties". With the band gap ranges from 0 to 0.8 eV [2]
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