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Cyclooctadiene iridium methoxide dimer is an organoiridium compound with the formula Ir 2 (OCH 3) 2 (C 8 H 12) 2, where C 8 H 12 is the diene 1,5-cyclooctadiene. It is a yellow solid that is soluble in organic solvents. The complex is used as a precursor to other iridium complexes, some of which are used in homogeneous catalysis. [1]
P(OCH 3) 3 → CH 3 P(O)(OCH 3) 2. As a ligand, trimethyl phosphite has a smaller cone angle and better acceptor properties relative to trimethylphosphine. A representative derivative is the colorless tetrahedral complex Ni(P(OMe) 3) 4 (m.p. 108 °C). [4] The tridentate ligand called the Kläui ligand is derived from trimethyl phosphite. The ...
The structure of a typical methoxy group. In organic chemistry, a methoxy group is the functional group consisting of a methyl group bound to oxygen.This alkoxy group has the formula R−O−CH 3.
C─X: fluoroalkanes: ordinary 1000–1100 trifluoromethyl 1100–1200 two strong, broad bands chloroalkanes: any 540–760 weak to medium bromoalkanes: any 500–600 medium to strong iodoalkanes: any 500 medium to strong N─O nitro compounds: aliphatic 1540 stronger 1380 weaker aromatic 1520 lower if conjugated 1350 P─C Organophosphorus ...
Trimethyl orthoformate is a useful building block for creating methoxymethylene groups and heterocyclic ring systems. It introduces a formyl group to a nucleophilic substrate, e.g. RNH 2 to form R-NH-CHO, which can undergo further reactions.
Trimethyl borate is the main precursor to sodium borohydride by its reaction with sodium hydride in the Brown-Schlesinger process: . 4 NaH + B(OCH 3) 3 → NaBH 4 + 3 NaOCH 3. It is a gaseous anti-oxidant in brazing and solder flux.
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Nitration of m-Nitrotoluene. The ortho effect also occurs when a meta-directing group is positioned in a meta arrangement relative to an ortho–para-directing group, a new substituent introduced into the molecule tends to preferentially occupy the ortho position relative to the meta-directing group rather than the para position.