Search results
Results from the WOW.Com Content Network
The concept of internal energy and its relationship to temperature. If a system has a definite temperature, then its total energy has three distinguishable components, termed kinetic energy (energy due to the motion of the system as a whole), potential energy (energy resulting from an externally imposed force field), and internal energy .
A concept related to the second law which is important in thermodynamics is that of reversibility. A process within a given isolated system is said to be reversible if throughout the process the entropy never increases (i.e. the entropy remains unchanged). Third law of thermodynamics = when =
For quasi-static and reversible processes, the first law of thermodynamics is: d U = δ Q − δ W {\displaystyle dU=\delta Q-\delta W} where δQ is the heat supplied to the system and δW is the work done by the system.
The above equation is a modern statement of the theorem. Nernst often used a form that avoided the concept of entropy. [1] Graph of energies at low temperatures. Another way of looking at the theorem is to start with the definition of the Gibbs free energy (G), G = H - TS, where H stands for enthalpy.
An important concept in thermodynamics is the thermodynamic system, which is a precisely defined region of the universe under study. Everything in the universe except the system is called the surroundings .
The first law of thermodynamics is essentially a definition of heat, i.e. heat is the change in the internal energy of a system that is not caused by a change of the external parameters of the system. However, the second law of thermodynamics is not a defining relation for the entropy.
Equilibrium thermodynamics, as a subject in physics, considers macroscopic bodies of matter and energy in states of internal thermodynamic equilibrium. It uses the concept of thermodynamic processes, by which bodies pass from one equilibrium state to another by transfer of matter and energy between them. The term 'thermodynamic system' is used ...
Classical thermodynamics deals with states of dynamic equilibrium.The state of a system at thermodynamic equilibrium is the one for which some thermodynamic potential is minimized (in the absence of an applied voltage), [2] or for which the entropy (S) is maximized, for specified conditions.