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NiCO 3 → NiO + CO 2. The nature of the resulting oxide depends on the nature of the precursor. The oxide obtained from the basic carbonate is often most useful for catalysis. Basic nickel carbonate can be made by treating solutions of nickel sulfate with sodium carbonate: 4 Ni 2+ + CO 2− 3 + 6 OH − + 4 H 2 O → Ni 4 CO 3 (OH) 6 (H 2 O) 4
The known salts include (NH 4) 2 Ni 2 (SO 4) 3, K 2 Ni 2 (SO 4) 3 and Rb 2 Ni 2 (SO 4) 3, and those of Tl and Cs are predicted to exist. Some minerals are double salts, for example Nickelzippeite Ni 2 (UO 2 ) 6 (SO 4 ) 3 (OH) 10 · 16H 2 O which is isomorphic to cobaltzippeite , magnesiozippeite and zinczippeite , part of the zippeite group.
The compound can be prepared by treating nickel or nickel(II) carbonate with acetic acid: . NiCO 3 + 2 CH 3 CO 2 H + 3 H 2 O → Ni(CH 3 CO 2) 2 ·4 H 2 O + CO 2. The mint-green tetrahydrate has been shown by X-ray crystallography to adopt an octahedral structure, the central nickel centre being coordinated by four water molecules and two acetate ligands. [5]
Nickel formate Ni(HCOO) 2.2 H 2 O decomposes when heated to yield carbon dioxide, carbon monoxide, hydrogen, water and finely divided porous nickel. [2] All the nickel atoms are six coordinated, but half have four water molecules and two formate oxygens close to the atom, and the other half are coordinated by six oxygens of formate groups.
This is a list of common chemical compounds with chemical formulae and CAS numbers, ... F 2 Ni: nickel difluoride: 10028-18-9 F 2 O: oxygen difluoride: 7783-41-7 F 2 OS:
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
Nickel(II) hydroxide is the inorganic compound with the formula Ni(OH) 2. It is a lime-green solid that dissolves with decomposition in ammonia and amines and is attacked by acids. It is electroactive, being converted to the Ni(III) oxy-hydroxide , leading to widespread applications in rechargeable batteries .
The bicarbonate ion (hydrogencarbonate ion) is an anion with the empirical formula HCO − 3 and a molecular mass of 61.01 daltons; it consists of one central carbon atom surrounded by three oxygen atoms in a trigonal planar arrangement, with a hydrogen atom attached to one of the oxygens.