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Molar concentration or molarity is most commonly expressed in units of moles of solute per litre of solution. [1] For use in broader applications, it is defined as amount of substance of solute per unit volume of solution, or per unit volume available to the species, represented by lowercase : [2]
M is the molar mass of the solvent. T b is boiling point of the pure solvent in kelvin. ΔH vap is the molar enthalpy of vaporization of the solvent. Through the procedure called ebullioscopy, a known constant can be used to calculate an unknown molar mass. The term ebullioscopy means "boiling measurement" in Latin.
The relative activity of a species i, denoted a i, is defined [4] [5] as: = where μ i is the (molar) chemical potential of the species i under the conditions of interest, μ o i is the (molar) chemical potential of that species under some defined set of standard conditions, R is the gas constant, T is the thermodynamic temperature and e is the exponential constant.
At 15.6 °C (60.1 °F), the density of a saturated solution is 0.88 g/ml; it contains 35.6% ammonia by mass, 308 grams of ammonia per litre of solution, and has a molarity of approximately 18 mol/L. At higher temperatures, the molarity of the saturated solution decreases and the density increases. [8]
The molar ionic strength, I, of a solution is a function of the concentration of all ions present in that solution. [3]= = where one half is because we are including both cations and anions, c i is the molar concentration of ion i (M, mol/L), z i is the charge number of that ion, and the sum is taken over all ions in the solution.
This page lists examples of the orders of magnitude of molar concentration. Source values are parenthesized where unit conversions were performed. M denotes the non-SI unit molar: 1 M = 1 mol/L = 10 −3 mol/m 3.
b is the molality of the solution. Through cryoscopy, a known constant can be used to calculate an unknown molar mass. The term "cryoscopy" means "freezing measurement" in Greek. Freezing point depression is a colligative property, so ΔT depends only on the number of solute particles dissolved, not the nature of those particles.
If the concentration of a sulfuric acid solution is c(H 2 SO 4) = 1 mol/L, then its normality is 2 N. It can also be called a "2 normal" solution. It can also be called a "2 normal" solution. Similarly, for a solution with c (H 3 PO 4 ) = 1 mol/L, the normality is 3 N because phosphoric acid contains 3 acidic H atoms.