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The grain per gallon (gpg) is a unit of water hardness defined as 1 grain (64.8 milligrams) of calcium carbonate dissolved in 1 US gallon of water (3.785412 L). It translates into 1 part in about 58,000 parts of water or 17.1 parts per million (ppm). Also called Clark degree (in terms of an imperial gallon).
The permanent hardness of water is determined by the water's concentration of cations with charges greater than or equal to 2+. Usually, the cations have a charge of 2+, i.e., they are divalent. Common cations found in hard water include Ca 2+ and Mg 2+, which frequently enter water supplies by leaching from minerals within aquifers.
Carbonate hardness, is a measure of the water hardness caused by the presence of carbonate (CO 2− 3) and bicarbonate (HCO − 3) anions. Carbonate hardness is usually expressed either in degrees KH (from the German "Karbonathärte"), or in parts per million calcium carbonate ( ppm CaCO 3 or grams CaCO 3 per litre|mg/L).
In water testing hardness is often measured in parts per million (ppm), where one part per million is defined as one milligram of calcium carbonate (CaCO 3) per litre of water. Consequently, 1 dGH corresponds to 10 ppm CaO but 17.848 ppm CaCO 3 which has a molar mass of 100.09 g/mol.
Carbonate hardness is a measure of the concentration of carbonates such as calcium carbonate (CaCO 3) and magnesium carbonate (MgCO 3) per volume of water. As a unit 1 dKH is the same as 1 °dH which is equal to approximately 0.1786 mmol/L or 10.02 milligrams (mg) of calcium carbonate per litre of water, i.e. 17.86 ppm.
14] Water can be classified by the level of total dissolved solids (TDS) in the water: Fresh water: TDS is less than 1,000 ppm. Brackish water: TDS = 1,000 to 10,000 ppm. Saline water: TDS = 10,000 to 35,000 ppm. Hypersaline: TDS greater than 35,000 ppm. Drinking water generally has a TDS below 500 ppm.
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