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log 10 of Acetonitrile vapor pressure. Uses formula log e P m m H g = {\displaystyle \scriptstyle \log _{e}P_{mmHg}=} log e ( 760 101.325 ) − 3.881710 log e ( T + 273.15 ) − 4999.618 T + 273.15 + 41.05901 + 3.515956 × 10 − 06 ( T + 273.15 ) 2 {\displaystyle \scriptstyle \log _{e}({\frac {760}{101.325}})-3.881710\log _{e}(T+ ...
This page contains tables of azeotrope data for various binary and ternary mixtures of solvents. The data include the composition of a mixture by weight (in binary azeotropes, when only one fraction is given, it is the fraction of the second component), the boiling point (b.p.) of a component, the boiling point of a mixture, and the specific gravity of the mixture.
2.79 6.55 –20.2 Diethyl ether: 0.713 34.5 2.16 –116.3 –1.79 K b & K f [1] Methanol [4] 0.79 64.7 Ethanol: 0.78 78.4 1.22 –114.6 –1.99 K b [2] Ethylene bromide: 2.18 133 6.43 9.974 –12.5 K b & K f [1] Ethylene glycol: 1.11 197.3 2.26 −12.9 –3.11 K b & K f [1] Formic acid: 101.0 2.4 8.0 –2.77 K b & K f [1] Naphthalene: 217.9 78. ...
In the table above, it can be seen that water is the most polar-solvent, followed by DMSO, and then acetonitrile. Consider the following acid dissociation equilibrium: HA ⇌ A − + H + Water, being the most polar-solvent listed above, stabilizes the ionized species to a greater extent than does DMSO or Acetonitrile.
Polar aprotic solvents: acetone (CH 3) 2 CO 56.1 °C 21.8 0.785 g/cm 3: 2.91 reacts with strong acids and bases acetonitrile : CH 3 CN 82 °C 38.3 0.776 g/cm 3: 3.20 reacts with strong acids and bases dichloromethane: CH 2 Cl 2: 39.6 °C 9.08 1.327 g/cm 3: 1.6 low boiling point dimethylacetamide (CH 3) 2 NCOCH 3: 165 °C 37.8 0.94 g/cm 3: 3.72 ...
Here is a similar formula from the 67th edition of the CRC handbook. Note that the form of this formula as given is a fit to the Clausius–Clapeyron equation, which is a good theoretical starting point for calculating saturation vapor pressures:
Acetonitrile is used mainly as a solvent in the purification of butadiene in refineries. Specifically, acetonitrile is fed into the top of a distillation column filled with hydrocarbons including butadiene, and as the acetonitrile falls down through the column, it absorbs the butadiene which is then sent from the bottom of the tower to a second separating tower.
The hydride surface can also be functionalized with carboxylic acids [2] and long-chain alkyl groups. [2] Mobile phases for ANPC are based on organic solvents as bulk solvents (such as methanol or acetonitrile) with a small amount of water as a modifier of polarity; thus, the mobile phase is both "aqueous" (water is present) and "normal phase ...