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An electron donating group (EDG) or electron releasing group (ERG, Z in structural formulas) is an atom or functional group that donates some of its electron density into a conjugated π system via resonance (mesomerism) or inductive effects (or induction)—called +M or +I effects, respectively—thus making the π system more nucleophilic.
An electron-withdrawing group (EWG) is a group or atom that has the ability to draw electron density toward itself and away from other adjacent atoms. [1] This electron density transfer is often achieved by resonance or inductive effects.
Delocalizing the radical ion stabilizes the transition state structure. As a result, the energy of activation decreases, enhancing the rate of the overall reaction. According to the captodative effect, the rate of a reaction is the greatest when both the EDG and EWG are able to delocalize the radical ion in the transition state structure. [7]
You may be familiar with the Environmental Working Group (EWG) because they release a list of the most pesticide-filled produce every year called The Dirty Dozen. They also establish the produce ...
EDG may refer to: Science and medicine. Electron donating group, a category in chemistry; Electrodermograph, a measuring device for skin;
The EWG withdraws electron density by resonance and effectively stabilizes the negative charge that is generated. The corresponding plot will show a positive rho value. In the case of a nucleophilic acyl substitution the effect of the substituent, X, of the non-leaving group can in fact accelerate the rate of the nucleophilic addition reaction ...
Life skills are often taught in the domain of parenting, either indirectly through the observation and experience of the child, or directly with the purpose of teaching a specific skill. Parenting itself can be considered as a set of life skills which can be taught or comes natural to a person. [13]
Elevational diversity gradient (EDG) is an ecological pattern where biodiversity changes with elevation. The EDG states that species richness tends to decrease as elevation increases, up to a certain point, creating a "diversity bulge" at middle elevations. There have been multiple hypotheses proposed for explaining the EDG, none of which ...