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The cooling rate of oil is much less than water. Intermediate rates between water and oil can be obtained with a purpose-formulated quenchant, a substance with an inverse solubility that therefore deposits on the object to slow the rate of cooling. Quenching can also be accomplished using inert gases, such as nitrogen and noble gases.
After heating the steel to the austenite phase and then quenching it in water, the microstructure will be in the martensitic phase. This is due to the fact that the steel will change from the austenite phase to the martensite phase after quenching. Some pearlite or ferrite may be present if the quench did not rapidly cool off all the steel. [4]
The high temperature of annealing may result in oxidation of the metal's surface, resulting in scale. If scale must be avoided, annealing is carried out in a special atmosphere, such as with endothermic gas (a mixture of carbon monoxide, hydrogen gas, and nitrogen gas). Annealing is also done in forming gas, a mixture of hydrogen and nitrogen.
Diagram of a cross section of a katana, showing the typical arrangement of the harder and softer zones. Differential hardening (also called differential quenching, selective quenching, selective hardening, or local hardening) is most commonly used in bladesmithing to increase the toughness of a blade while keeping very high hardness and strength at the edge.
Many different methods and cooling baths for quenching have been attempted during ancient times, from quenching in urine, blood, or metals like mercury or lead, but the process of tempering has remained relatively unchanged over the ages. Tempering was often confused with quenching and, often, the term was used to describe both techniques.
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Similarly, by annealing (and thus allowing for slow structural relaxation) the glass structure in time approaches an equilibrium density corresponding to the supercooled liquid at this same temperature. T g is located at the intersection between the cooling curve (volume versus temperature) for the glassy state and the supercooled liquid.
The most notable difference between austempering and conventional quench and tempering is that it involves holding the workpiece at the quenching temperature for an extended period of time. The basic steps are the same whether applied to cast iron or steel and are as follows: