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Lead (IV) hydroxide, Pb (OH)4, also called ortho-plumbic acid, is the notional conjugate acid of the ortho- plumbate (IV) ion, PbO4− 4, found in compounds such as calcium orthoplumbate, Ca2PbO4. [citation needed] Like its tin analog Sn (OH)4, Pb (OH)4 has not been isolated.
Careful hydrolysis of lead(II) acetate solution yields a crystalline product with a formula 6PbO·2H 2 O or Pb 6 O 4 (OH) 4. [3] This material is a cluster compound, consisting of an octahedron of Pb centers, each face of which is capped by an oxide or a hydroxide. The structure is reminiscent of the Mo 6 S 8 subunit of the Chevrel phases. [4]
The molar mass of atoms of an element is given by the relative atomic mass of the element multiplied by the molar mass constant, M u ≈ 1.000 000 × 10 −3 kg/mol = 1 g/mol. For normal samples from earth with typical isotope composition, the atomic weight can be approximated by the standard atomic weight [ 2 ] or the conventional atomic weight.
Lead chromate adopts the monazite structure, meaning that the connectivity of the atoms is very similar to other compounds of the type MM'O 4. Pb(II) has a distorted coordination sphere being surrounded by eight oxides with Pb-O distances ranging from 2.53 to 2.80 Å. The chromate anion is tetrahedral, as usual. [3]
Lead (IV) oxide, commonly known as lead dioxide, is an inorganic compound with the chemical formula PbO2. It is an oxide where lead is in an oxidation state of +4. [ 1 ] It is a dark-brown solid which is insoluble in water. [ 2 ] It exists in two crystalline forms.
Contents. Lead carbonate. Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N verify (what is YN ?) Lead (II) carbonate is the chemical compound with the chemical formula PbCO3. It is a white, toxic solid. [ 2 ] It occurs naturally as the mineral cerussite.
The basic hydroxo complex [Pb 6 O(OH) 6] 4+ is a cluster of six lead centres with metal–metal bonds surrounding a central oxide ion. The six hydroxide groups lie on the faces of the two external Pb 4 tetrahedra. In strongly alkaline solutions soluble plumbate ions are formed, including [Pb(OH) 6] 2−. [28]
Lead's close-packed face-centered cubic structure and high atomic weight result in a density [23] of 11.34 g/cm 3, which is greater than that of common metals such as iron (7.87 g/cm 3), copper (8.93 g/cm 3), and zinc (7.14 g/cm 3). [24] This density is the origin of the idiom to go over like a lead balloon.