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  2. Completing the square - Wikipedia

    en.wikipedia.org/wiki/Completing_the_square

    That is, h is the x-coordinate of the axis of symmetry (i.e. the axis of symmetry has equation x = h), and k is the minimum value (or maximum value, if a < 0) of the quadratic function. One way to see this is to note that the graph of the function f ( x ) = x 2 is a parabola whose vertex is at the origin (0, 0).

  3. Linear molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Linear_molecular_geometry

    As described by the VSEPR model, the five valence electron pairs on the central atom form a trigonal bipyramid in which the three lone pairs occupy the less crowded equatorial positions and the two bonded atoms occupy the two axial positions at the opposite ends of an axis, forming a linear molecule.

  4. Berry mechanism - Wikipedia

    en.wikipedia.org/wiki/Berry_mechanism

    Trigonal bipyramidal molecular shape ax = axial ligands (on unique axis) eq = equatorial ligand (in plane perpendicular to unique axis). The Berry mechanism, or Berry pseudorotation mechanism, is a type of vibration causing molecules of certain geometries to isomerize by exchanging the two axial ligands (see the figure) for two of the equatorial ones.

  5. Rotation formalisms in three dimensions - Wikipedia

    en.wikipedia.org/wiki/Rotation_formalisms_in...

    This is Rodrigues' formula for the axis of a composite rotation defined in terms of the axes of the two component rotations. He derived this formula in 1840 (see page 408). [3] The three rotation axes A, B, and C form a spherical triangle and the dihedral angles between the planes formed by the sides of this triangle are defined by the rotation ...

  6. Square pyramidal molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Square_pyramidal_molecular...

    Structure of xenon oxytetrafluoride, an example of a molecule with the square pyramidal coordination geometry. Square pyramidal geometry describes the shape of certain chemical compounds with the formula ML 5 where L is a ligand. If the ligand atoms were connected, the resulting shape would be that of a pyramid with a square base.

  7. Octahedral molecular geometry - Wikipedia

    en.wikipedia.org/wiki/Octahedral_molecular_geometry

    For ML a 4 L b 2, two isomers exist.These isomers of ML a 4 L b 2 are cis, if the L b ligands are mutually adjacent, and trans, if the L b groups are situated 180° to each other. It was the analysis of such complexes that led Alfred Werner to the 1913 Nobel Prize–winning postulation of octahedral complexes.

  8. Mass spectrum - Wikipedia

    en.wikipedia.org/wiki/Mass_spectrum

    The x-axis of a mass spectrum represents a relationship between the mass of a given ion and the number of elementary charges that it carries. This is written as the IUPAC standard m/z to denote the quantity formed by dividing the mass of an ion (in daltons) by the dalton unit and by its charge number (positive absolute value).

  9. Quadratic equation - Wikipedia

    en.wikipedia.org/wiki/Quadratic_equation

    For the quadratic function y = x 2 − x − 2, the points where the graph crosses the x-axis, x = −1 and x = 2, are the solutions of the quadratic equation x 2 − x − 2 = 0. The process of completing the square makes use of the algebraic identity + + = (+), which represents a well-defined algorithm that can be used to solve any quadratic ...