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Boltzmann constant: The Boltzmann constant, k, is one of seven fixed constants defining the International System of Units, the SI, with k = 1.380 649 x 10 −23 J K −1. The Boltzmann constant is a proportionality constant between the quantities temperature (with unit kelvin) and energy (with unit joule).
The Stefan–Boltzmann constant, σ, is derived from other known physical constants: = where k is the Boltzmann constant, the h is the Planck constant, and c is the speed of light in vacuum. [19] [4]: 388
Boltzmann's equation—carved on his gravestone. [1]In statistical mechanics, Boltzmann's equation (also known as the Boltzmann–Planck equation) is a probability equation relating the entropy, also written as , of an ideal gas to the multiplicity (commonly denoted as or ), the number of real microstates corresponding to the gas's macrostate:
kT (also written as k B T) is the product of the Boltzmann constant, k (or k B), and the temperature, T.This product is used in physics as a scale factor for energy values in molecular-scale systems (sometimes it is used as a unit of energy), as the rates and frequencies of many processes and phenomena depend not on their energy alone, but on the ratio of that energy and kT, that is, on E ...
These include the Boltzmann constant, which gives the correspondence of the dimension temperature to the dimension of energy per degree of freedom, and the Avogadro constant, which gives the correspondence of the dimension of amount of substance with the dimension of count of entities (the latter formally regarded in the SI as being dimensionless).
= , where k B is the Boltzmann constant, and Ω denotes the volume of macrostate in the phase space or otherwise called thermodynamic probability. d S = δ Q T {\displaystyle dS={\frac {\delta Q}{T}}} , for reversible processes only
The proportionality constant k B is one of the fundamental constants of physics and is named the Boltzmann constant in honor of its discoverer. Boltzmann's entropy describes the system when all the accessible microstates are equally likely. It is the configuration corresponding to the maximum of entropy at equilibrium.
k B is the Boltzmann constant; T is the absolute temperature. Note that the mobility μ = v d /F can be calculated based on the viscosity of the gas; Therefore, the Einstein–Smoluchowski equation also provides a relation between the mass diffusivity and the viscosity of the gas.