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The infrared atmospheric window is an atmospheric window in the infrared spectrum where there is relatively little absorption of terrestrial thermal radiation by atmospheric gases. [1] The window plays an important role in the atmospheric greenhouse effect by maintaining the balance between incoming solar radiation and outgoing IR to space.
Water vapor is a greenhouse gas in the Earth's atmosphere, responsible for 70% of the known absorption of incoming sunlight, particularly in the infrared region, and about 60% of the atmospheric absorption of thermal radiation by the Earth known as the greenhouse effect. [25]
The method or technique of infrared spectroscopy is conducted with an instrument called an infrared spectrometer (or spectrophotometer) which produces an infrared spectrum. An IR spectrum can be visualized in a graph of infrared light absorbance (or transmittance ) on the vertical axis vs. frequency , wavenumber or wavelength on the horizontal ...
The absorption patterns of water vapor (blue peaks) and carbon dioxide (pink peaks) overlap in some wavelengths. [ 33 ] Water vapor is the most important greenhouse gas overall, being responsible for 41–67% of the greenhouse effect, [ 31 ] [ 32 ] but its global concentrations are not directly affected by human activity.
Water vapor absorbing these wavelengths of IR energy is mainly attributed to water being a polar molecule. Water's polarity allows it to absorb and release radiation at far, near and mid-infrared wavelengths. [6] The polarity also largely impacts how water interacts with nature, for it allows complexes of water, such as the water dimer. [6]
Greenhouse gases in the atmosphere are responsible for a majority of the absorption of longwave radiation in the atmosphere. The most important of these gases are water vapor, carbon dioxide, methane, and ozone. [22] The absorption of longwave radiation by gases depends on the specific absorption bands of the gases in the atmosphere. [19]
Fourier transform infrared spectroscopy (FTIR) [1] is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectral range.
These absorption characteristics make infrared analyzers an invaluable tool in geoscience, environmental science, and atmospheric science. For instance, atmospheric gas monitoring has been facilitated by the development of commercially available gas analyzers which can distinguish between carbon dioxide, methane, carbon monoxide, oxygen, and ...