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Rechargeable lithium metal batteries are secondary lithium metal batteries.They have metallic lithium as a negative electrode.The high specific capacity of lithium metal (3,860 mAh g −1), very low redox potential (−3.040 V versus standard hydrogen electrode) and low density (0.59 g cm −3) make it the ideal negative material for high energy density battery technologies. [1]
Lithium batteries are widely used in portable consumer electronic devices. The term "lithium battery" refers to a family of different lithium-metal chemistries, comprising many types of cathodes and electrolytes but all with metallic lithium as the anode. The battery requires from 0.15 to 0.3 kg (5 to 10 oz) of lithium per kWh.
Anode-free lithium ion batteries have been demonstrated using a variety of cathode materials, such as LiFePO 4, LiCoO 2, and LiNi 1/3 Mn 1/3 Co 1/3 (NMC 111).. These intercalation-type cathodes typically offer limited Li content (14.3 at.% for LiFePO4, 25 at.% for LiCoO2 and LiNixCoyMn1-x-yO2), although they remain the primary research targets. [2]
A lithium-ion or Li-ion battery is a type of rechargeable battery that uses the reversible intercalation of Li + ions into electronically conducting solids to store energy. In comparison with other commercial rechargeable batteries, Li-ion batteries are characterized by higher specific energy, higher energy density, higher energy efficiency, a longer cycle life, and a longer calendar life.
The lithium iron phosphate battery (LiFePO 4 battery) or LFP battery (lithium ferrophosphate) is a type of lithium-ion battery using lithium iron phosphate (LiFePO 4) as the cathode material, and a graphitic carbon electrode with a metallic backing as the anode.
He also invented the first rechargeable lithium metal battery (LMB), patented in 1977 and assigned to Exxon for commercialization in small devices and electric vehicles. Whittingham's rechargeable lithium metal battery is based on a LiAl anode and an intercalation-type TiS 2 cathode. His work on lithium batteries laid the foundation for others ...
A metal–air electrochemical cell is an electrochemical cell that uses an anode made from pure metal and an external cathode of ambient air, typically with an aqueous or aprotic electrolyte. [1] [2] During discharging of a metal–air electrochemical cell, a reduction reaction occurs in the ambient air cathode while the metal anode is oxidized.
A lithium-titanate battery is a modified lithium-ion battery that uses lithium-titanate nanocrystals, instead of carbon, on the surface of its anode.This gives the anode a surface area of about 100 square meters per gram, compared with 3 square meters per gram for carbon, allowing electrons to enter and leave the anode quickly.
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