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A state of thermodynamic equilibrium endures unchangingly unless it is interrupted by a thermodynamic operation that initiates a thermodynamic process. The equilibrium states are each respectively fully specified by a suitable set of thermodynamic state variables, that depend only on the current state of the system, not on the path taken by the ...
A thermodynamic system is a macroscopic object, the microscopic details of which are not explicitly considered in its thermodynamic description. The number of state variables required to specify the thermodynamic state depends on the system, and is not always known in advance of experiment; it is usually found from experimental evidence.
This Process Path is a straight horizontal line from state one to state two on a P-V diagram. Figure 2. It is often valuable to calculate the work done in a process. The work done in a process is the area beneath the process path on a P-V diagram. Figure 2 If the process is isobaric, then the work done on the piston is easily calculated.
Path functions depend on the path taken to reach one state from another. Different routes give different quantities. Examples of path functions include work, heat and arc length. In contrast to path functions, state functions are independent of the path taken. Thermodynamic state variables are point functions, differing from path functions. For ...
During a closed cycle, the system returns to its original thermodynamic state of temperature and pressure. Process quantities (or path quantities), such as heat and work are process dependent. For a cycle for which the system returns to its initial state the first law of thermodynamics applies: = =
In thermodynamic integration, the free energy difference is calculated by defining a thermodynamic path between the states and integrating over ensemble-averaged enthalpy changes along the path. Such paths can either be real chemical processes or alchemical processes. An example alchemical process is the Kirkwood's coupling parameter method. [1]
The thermodynamic parameters may now be thought of as variables and the state may be thought of as a particular point in a space of thermodynamic parameters. The change in the state of the system can be seen as a path in this state space. This change is called a thermodynamic process. Thermodynamic equations are now used to express the ...
Thermodynamics is a branch of physics that deals with heat, work, ... or on the path through intermediate steps, by which the system arrived at its state.