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Dimethyl-4-phenylenediamine can be converted to methylene blue by reaction with dimethylaniline and sodium thiosulfate in several steps: [3] It is used as accelerator for the vulcanization of rubber, being first converted to the corresponding mercaptobenzothiazole.
The phenylenediamine reacts with aldehydes to yield Schiff bases according to the following reaction: [9] R−CHO + H 2 N−C 6 H 4 −NH 2 → R−CH=N−C 6 H 4 −NH 2 + H 2 O. Products of this reaction are yellow to red in colour. Most β-orcinol depsidones and some β-orcinol depsides will react positively. [11]
p-Phenylenediamine (PPD) is an organic compound with the formula C 6 H 4 (NH 2) 2. This derivative of aniline is a white solid, but samples can darken due to air oxidation. [1] It is mainly used as a component of engineering polymers and composites like kevlar. It is also an ingredient in hair dyes and is occasionally used as a substitute for ...
6PPD is an organic chemical widely used as stabilising additive (or antidegradant) in rubbers, such as NR, SBR and BR; all of which are common in vehicle tires. [1] Although it is an effective antioxidant it is primarily used because of its excellent antiozonant performance.
The final step of the reaction is an elimination reaction (specifically an E2 reaction), which involves the extraction of the other hydrogen that was once benzylic, before the bicyclic compound was formed, whose electrons are converted into a new pi-bond in the ring system. This allows the pi-bond formed by nitrogen in the preceding step to be ...
Synthesis of benzotriazole involves the reaction of o-phenylenediamine, sodium nitrite, and acetic acid. The conversion proceeds via diazotization of one of the amine groups: [7] [8] The synthesis can be improved when the reaction is carried out at low temperatures (5–10 °C) and briefly sonicated in an ultrasonic bath. [9]
m-Phenylenediamine, also called 1,3-diaminobenzene, is an organic compound with the formula C 6 H 4 (NH 2) 2.It is an isomer of o-phenylenediamine and p-phenylenediamine.This aromatic diamine is a colourless solid that appears as needles, but turns red or purple on exposure to air due to formation of oxidation products. [3]
Wurster's blue is the radical cation of the colorless chemical N,N,N′,N′-tetramethyl-p-phenylenediamine, also known as TMPD. [1] This is an easily oxidized phenylenediamine, which loses two electrons in one-electron oxidation steps; the radical cation is a characteristic blue-violet color, which gives the compound part of its name.