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Isotopomers or isotopic isomers are isomers with isotopic atoms, having the same number of each isotope of each element but differing in their positions in the molecule. The result is that the molecules are either constitutional isomers or stereoisomers solely based on isotopic location.
In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. [1] Isomerism refers to the existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties.
The term isotopes (originally also isotopic elements, [4] now sometimes isotopic nuclides [5]) is intended to imply comparison (like synonyms or isomers). For example, the nuclides 12 6 C, 13 6 C, 14 6 C are isotopes (nuclides with the same atomic number but different mass numbers [6]), but 40 18 Ar, 40 19 K, 40 20 Ca are isobars (nuclides with ...
In chemistry, isotopologues (also spelled isotopologs) are molecules that differ only in their isotopic composition. [1] They have the same chemical formula and bonding arrangement of atoms, but at least one atom has a different number of neutrons than the parent.
^ Tantalum-180m is a "metastable isotope", meaning it is an excited nuclear isomer of tantalum-180. See isotopes of tantalum . However, the half-life of this nuclear isomer is so long that it has never been observed to decay, and it thus is an "observationally stable" primordial nuclide , a rare isotope of tantalum.
A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by (possibly large) barriers in the potential energy. During a metastable state of finite lifetime, all state-describing parameters reach and hold stationary values.
Owing to both of these advantages, the method of isotope dilution is regarded among chemistry measurement methods of the highest metrological standing. [1] Isotopes are variants of a particular chemical element which differ in neutron number. All isotopes of a given element have the same number of protons in each atom.
In contrast, the proton numbers for which there are no stable isotopes are 43, 61, and 83 or more (83, 90, 92, and perhaps 94 have primordial radionuclides). [3] This is related to nuclear magic numbers , the number of nucleons forming complete shells within the nucleus, e.g. 2, 8, 20, 28, 50, 82, and 126.