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Carbene radicals, in which the carbene is bonded to an open-shell metal with the carbene carbon possessing a radical character. Carbene radicals have features of both Fischer and Schrock carbenes, but are typically long-lived reaction intermediates. The "second generation" of the Grubbs catalysts for alkene metathesis features an NHC ligand.
An M4 carbine, a common AR-15–style carbine. The M4 is the shorter, lighter carbine variant of the M16 rifle.. A carbine (/ ˈ k ɑːr b iː n / KAR-been or / ˈ k ɑːr b aɪ n / KAR-byn) [1] is a long gun that has a barrel shortened from its original length. [2]
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Carbene complexes have been synthesized from most transition metals and f-block metals, [2] using many different synthetic routes such as nucleophilic addition and alpha-hydrogen abstraction. [1] The term carbene ligand is a formalism since many are not directly derived from carbenes and most are much less reactive than lone carbenes. [2]
The net reaction gives a transition metal carbene complex: L n M≡CR + HX → L n (X)M=CHR. These complexes can also undergo photochemical reactions. In some carbyne complexes, coupling of the carbyne ligand to a carbonyl is observed. Protonation of the carbyne carbon and conversion of the carbyne ligand into a π-allyl. [13]
Google Translate is a multilingual neural machine translation service developed by Google to translate text, documents and websites from one language into another. It offers a website interface, a mobile app for Android and iOS, as well as an API that helps developers build browser extensions and software applications. [3]
Methylene (IUPAC name: Methylidene, also called carbene or methene) is an organic compound with the chemical formula CH 2 (also written [CH 2] and not to be confused with compressed hydrogen, which is also denoted CH 2). It is a colourless gas that fluoresces in the mid-infrared range, and only persists in dilution, or as an adduct.
Google Dictionary is an online dictionary service of Google that can be accessed with the "define" operator and other similar phrases [note 1] in Google Search. [2] It is also available in Google Translate and as a Google Chrome extension. The dictionary content is licensed from Oxford University Press's Oxford Languages. [3]