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Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials (usually a metal) by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion. [1] [2]
If the aluminium foil was not used with a dissimilar metal container, the reaction was probably a chemical one. It is possible for heavy concentrations of salt, vinegar or some other acidic compounds to cause the foil to disintegrate. The product of either of these reactions is an aluminium salt. It does not harm the food, but any deposit may ...
The rate of corrosion is affected by water and accelerated by electrolytes, as illustrated by the effects of road salt on the corrosion of automobiles. The key reaction is the reduction of oxygen: O 2 + 4 e − + 2 H 2 O → 4 OH −. Because it forms hydroxide ions, this process is strongly affected by the presence of acid. Likewise, the ...
Galvanic corrosion is the electrochemical erosion of metals. Corrosion occurs when two dissimilar metals are in contact with each other in the presence of an electrolyte, such as salt water. This forms a galvanic cell, with hydrogen gas forming on the more noble (less active) metal.
High-temperature corrosion is a mechanism of corrosion that takes place when gas turbines, diesel engines, furnaces or other machinery come in contact with hot gas containing certain contaminants. Fuel sometimes contains vanadium compounds or sulfates, which can form low melting point compounds during combustion.
The galvanic series (or electropotential series) determines the nobility of metals and semi-metals. When two metals are submerged in an electrolyte, while also electrically connected by some external conductor, the less noble (base) will experience galvanic corrosion. The rate of corrosion is determined by the electrolyte, the difference in ...
Instead of applying the acid solution directly to the metal parts, the parts are placed in a sealed cabinet with a moisture source, a container of nitric acid and a container of hydrochloric acid. The mixed fumes of the acids produce a uniform rust on the surface of the parts (inside and out) in about 12 hours.
In brief, corrosion is a chemical reaction occurring by an electrochemical mechanism (a redox reaction). [1] During corrosion of iron or steel there are two reactions, oxidation (equation 1), where electrons leave the metal (and the metal dissolves, i.e. actual loss of metal results) and reduction, where the electrons are used to convert oxygen and water to hydroxide ions (equation 2): [2]