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Classically, the Franck–Condon principle is the approximation that an electronic transition is most likely to occur without changes in the positions of the nuclei in the molecular entity and its environment. The resulting state is called a Franck–Condon state, and the transition involved, a vertical transition.
Atomic electron transition. An electron in a Bohr model atom, moving from quantum level n = 3 to n = 2 and releasing a photon. The energy of an electron is determined by its orbit around the atom. The n = 0 orbit, commonly referred to as the ground state, has the lowest energy of all states in the system. In atomic physics and chemistry, an ...
Radioactive decay is the process of emission of particles and energy from the unstable nucleus of an atom to form a stable product. This is done via the tunnelling of a particle out of the nucleus (an electron tunneling into the nucleus is electron capture). This was the first application of quantum tunnelling.
In chemistry, molecular orbital theory (MO theory or MOT) is a method for describing the electronic structure of molecules using quantum mechanics. It was proposed early in the 20th century. The MOT explains the paramagnetic nature of O 2, which VSEPR theory cannot explain. In molecular orbital theory, electrons in a molecule are not assigned ...
Emission spectrum of a ceramic metal halide lamp. The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference ...
t. e. Spontaneous emission is the process in which a quantum mechanical system (such as a molecule, an atom or a subatomic particle) transits from an excited energy state to a lower energy state (e.g., its ground state) and emits a quantized amount of energy in the form of a photon. Spontaneous emission is ultimately responsible for most of the ...
Electron transfer. Electron transfer (ET) occurs when an electron relocates from an atom or molecule to another such chemical entity. ET is a mechanistic description of certain kinds of redox reactions involving transfer of electrons. [2] Electrochemical processes are ET reactions.
Electron excitation. Electron excitation is the transfer of a bound electron to a more energetic, but still bound state. This can be done by photoexcitation (PE), where the electron absorbs a photon and gains all its energy [1] or by collisional excitation (CE), where the electron receives energy from a collision with another, energetic ...