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In chemistry, isomers are molecules or polyatomic ions with identical molecular formula – that is, the same number of atoms of each element – but distinct arrangements of atoms in space. [1] Isomerism refers to the existence or possibility of isomers. Isomers do not necessarily share similar chemical or physical properties.
Functional isomers are structural isomers which have different functional groups, resulting in significantly different chemical and physical properties. [ 11 ] An example is the pair propanal H 3 C–CH 2 –C(=O)-H and acetone H 3 C–C(=O)–CH 3 : the first has a –C(=O)H functional group, which makes it an aldehyde , whereas the second has ...
In chemistry, metamerism is used to define the isomeric relationship between compounds with the same polyvalent, heteroatomic, functional group but differ in the main carbon chain or any of the side chains. It has rather been an obsolete term for isomerism, which has not been recognised by IUPAC in its publications. [1]
The following is a list of straight-chain alkanes, the total number of isomers of each (including branched chains), ... 8 227 162 372 221 203: 3 773 978 539 594 435 261:
In organic chemistry, an anti-Bredt molecule is a bridged molecule with a double bond at the bridgehead. Bredt's rule is the empirical observation that such molecules only form in large ring systems. For example, two of the following norbornene isomers violate Bredt's rule, and are too unstable to prepare: Bridgehead atoms violating Bredt's ...
Two kinds of stereoisomers. In stereochemistry, stereoisomerism, or spatial isomerism, is a form of isomerism in which molecules have the same molecular formula and sequence of bonded atoms (constitution), but differ in the three-dimensional orientations of their atoms in space.
Isomers themselves exist in many varieties but can generally be classified as structural isomers or stereoisomers. Structural isomers have a different ordering of bonds and/or different bond connectivity from one another, as in the case of hexane and its four other isomeric forms ( 2-methylpentane , 3-methylpentane , 2,2-dimethylbutane , and 2 ...
Isotopomers of isotopically modified ethanol. The molecule at the bottom left is not an isotopomer of any other depicted molecule. Isotopomers or isotopic isomers are isomers which differ by isotopic substitution, and which have the same number of atoms of each isotope but in a different arrangement.