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2-Methyl-2-butene, 2m2b, 2-methylbut-2-ene, beta-isoamylene, or Trimmethylethylene is an alkene hydrocarbon with the molecular formula C 5 H 10. Used as a free radical scavenger in trichloromethane (chloroform) and dichloromethane (methylene chloride). It is also used to scavenge hypochlorous acid (HOCl) in the Pinnick oxidation.
An illustrative example is the epoxidation of trans-2-butene with m-CPBA to give trans-2,3-epoxybutane: [4] The oxygen atom that adds across the double bond of the alkene is taken from the peroxy acid, generating a molecule of the corresponding carboxylic acid as a byproduct.
For example, of the isomers of butene, the two methyl groups of (Z)-but-2-ene (a.k.a. cis-2-butene) appear on the same side of the double bond, and in (E)-but-2-ene (a.k.a. trans-2-butene) the methyl groups appear on opposite sides. These two isomers of butene have distinct properties.
For example, when 2-iodobutane is treated with alcoholic potassium hydroxide (KOH), but-2-ene is the major product and but-1-ene is the minor product. [ 1 ] More generally, Zaytsev's rule predicts that in an elimination reaction the most substituted product will be the most stable, and therefore the most favored.
2-Methyl-2-butene (CAS 513-35-9) Index of chemical compounds with the same molecular formula This set index page lists chemical structure articles associated with the same molecular formula .
Isobutylene (or 2-methylpropene) is a hydrocarbon with the chemical formula (CH 3) 2 C=CH 2. It is a four-carbon branched alkene (olefin), one of the four isomers of butylene . It is a colorless flammable gas, and is of considerable industrial value.
2-Methyl-2-butene is often used in this context: Resorcinol and sulfamic acid are also common scavenger reagents. [6] [7] Hydrogen peroxide (H 2 O 2) can be used as HOCl scavenger whose byproducts do not interfere in the Pinnick oxidation reaction: HOCl + H 2 O 2 → HCl + O 2 + H 2 O
Lindgren oxidation is a selective method for oxidizing aldehydes to carboxylic acids. [1] The reaction is named after Bengt O. Lindgren. The oxidation takes place in water containing solvent mixtures under slightly acidic conditions (pH 3–5) with sodium chlorite as oxidizer.