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At first solid electrodes were used in the Grove cell, Francis Thomas Bacon was the first to use gas diffusion electrodes for the Bacon fuel cell, [3] converting hydrogen and oxygen at high temperature into electricity. Over the years, gas diffusion electrodes have been adapted for various other processes like: Zinc-air battery since 1980
Gas-diffusion electrocrystallization (GDEx) is an electrochemical process consisting on the reactive precipitation of metal ions in solution (or dispersion) with intermediaries produced by the electrochemical reduction of gases (such as oxygen), at gas diffusion electrodes.
The nickel–hydrogen battery combines the positive nickel electrode of a nickel–cadmium battery and the negative electrode, including the catalyst and gas diffusion elements, of a fuel cell. During discharge, hydrogen contained in the pressure vessel is oxidized into water while the nickel oxyhydroxide electrode is reduced to nickel hydroxide.
PEMFCs are built out of membrane electrode assemblies (MEA) which include the electrodes, electrolyte, catalyst, and gas diffusion layers. An ink of catalyst, carbon, and electrode are sprayed or painted onto the solid electrolyte and carbon paper is hot pressed on either side to protect the inside of the cell and also act as electrodes.
The two electrodes are separated by a porous matrix saturated with an aqueous alkaline solution, such as potassium hydroxide (KOH). Aqueous alkaline solutions do not reject carbon dioxide (CO 2) so the fuel cell can become "poisoned" through the conversion of KOH to potassium carbonate (K 2 CO 3). [2]
The planar fuel cell design geometry is the typical sandwich type geometry employed by most types of fuel cells, where the electrolyte is sandwiched in between the electrodes. SOFCs can also be made in tubular geometries where either air or fuel is passed through the inside of the tube and the other gas is passed along the outside of the tube.
The magnitude of the current is controlled by how much of the target gas is oxidized at the working electrode. Sensors are usually designed so that the gas supply is limited by diffusion, and thus the output from the sensor is linearly proportional to the gas concentration. This linear output is one of the advantages of electrochemical sensors ...
This configuration allows for efficient proton conduction and effective gas diffusion, making it suitable for various applications, including fuel cell vehicles and portable power systems. Research has shown that 5-layer MEAs can provide improved performance under different operating conditions, making them a preferred choice in the industry.