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The reaction of phosphorus pentoxide and PCl 5 produces POCl 3 : [18] [page needed] 6 PCl 5 + P 4 O 10 → 10 POCl 3. PCl 5 chlorinates nitrogen dioxide to form unstable nitryl chloride: PCl 5 + 2 NO 2 → PCl 3 + 2 NO 2 Cl 2 NO 2 Cl → 2 NO 2 + Cl 2. PCl 5 is a precursor for lithium hexafluorophosphate, LiPF 6.
The reaction of phosphorus pentachloride (PCl 5) with phosphorus pentoxide (P 4 O 10). 6 PCl 5 + P 4 O 10 → 10 POCl 3. The reaction can be simplified by chlorinating a mixture of PCl 3 and P 4 O 10, generating the PCl 5 in situ. The reaction of phosphorus pentachloride with boric acid or oxalic acid: [12] 3 PCl 5 + 2 B(OH) 3 → 3 POCl 3 + B ...
PCl 5: −440 Phosphorus pentachloride: Gas PCl 5: −321 Phosphorus pentoxide: Solid P 2 O 5: −1505.5 [6] Potassium bromide: Solid KBr −392.2 Potassium carbonate: Solid K 2 CO 3: −1150 Potassium chlorate: Solid KClO 3: −391.4 Potassium chloride: Solid KCl −436.68 Potassium fluoride: Solid KF −562.6 Potassium oxide: Solid K 2 O − ...
A pentachloride is a compound or ion that contains five chlorine atoms or ions. Common pentachlorides include: Antimony pentachloride, SbCl 5; Arsenic pentachloride, AsCl 5 ...
Phosphorus pentachloride, phosphorus pentabromide, and phosphorus heptabromide are ionic in the solid and liquid states; PCl 5 is formulated as PCl 4 + PCl 6 –, but in contrast, PBr 5 is formulated as PBr 4 + Br −, and PBr 7 is formulated as PBr 4 + Br 3 −. They are widely used as chlorinating and brominating agents in organic chemistry.
PCl 3 is important indirectly as a precursor to PCl 5, POCl 3 and PSCl 3, which are used in many applications, including herbicides, insecticides, plasticisers, oil additives, and flame retardants. For example, oxidation of PCl 3 gives POCl 3 , which is used for the manufacture of triphenyl phosphate and tricresyl phosphate , which find ...
Hexachlorophosphazene is an inorganic compound with the chemical formula (N P Cl 2) 3.The molecule has a cyclic, unsaturated backbone consisting of alternating phosphorus and nitrogen atoms, and can be viewed as a trimer of the hypothetical compound N≡PCl 2 (phosphazyl dichloride).
2 Ta + 5 Cl 2 → 2 TaCl 5 2 Ta + 10 HCl → 2 TaCl 5 + 5 H 2. It can also be prepared by a reaction between tantalum pentoxide and thionyl chloride at 240 °C Ta 2 O 5 + 5 SOCl 2 → 2 TaCl 5 + 5 SO 2. Tantalum pentachloride is commercially available, however samples can be contaminated with tantalum(V) oxychloride (TaOCl 3), formed by hydrolysis.