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Triple bonds are stronger than the equivalent single bonds or double bonds, with a bond order of three. The most common triple bond is in a nitrogen N 2 molecule; the second most common is that between two carbon atoms, which can be found in alkynes. Other functional groups containing a triple bond are cyanides and isocyanides.
Here the sum extends over π molecular orbitals only, and n i is the number of electrons occupying orbital i with coefficients c ri and c si on atoms r and s respectively. Assuming a bond order contribution of 1 from the sigma component this gives a total bond order (σ + π) of 5/3 = 1.67 for benzene, rather than the commonly cited bond order ...
In chemistry, azide (/ ˈ eɪ z aɪ d /, AY-zyd) is a linear, polyatomic anion with the formula N − 3 and structure − N=N + =N −.It is the conjugate base of hydrazoic acid HN 3. Organic azides are organic compounds with the formula RN 3, containing the azide functional group. [1]
Many stoichiometric phases are usually present for most elements (e.g. MnN, Mn 6 N 5, Mn 3 N 2, Mn 2 N, Mn 4 N, and Mn x N for 9.2 < x < 25.3). They may be classified as "salt-like" (mostly ionic), covalent, "diamond-like", and metallic (or interstitial ), although this classification has limitations generally stemming from the continuity of ...
A CN bond is strongly polarized towards nitrogen (the electronegativities of C and N are 2.55 and 3.04, respectively) and subsequently molecular dipole moments can be high: cyanamide 4.27 D, diazomethane 1.5 D, methyl azide 2.17, pyridine 2.19. For this reason many compounds containing CN bonds are water-soluble.
Molecular orbital diagram of dinitrogen molecule, N 2. There are five bonding orbitals and two antibonding orbitals (marked with an asterisk; orbitals involving the inner 1s electrons not shown), giving a total bond order of three. Atomic nitrogen, also known as active nitrogen, is highly reactive, being a triradical with three unpaired electrons.
The bond valence method or mean method (or bond valence sum) (not to be mistaken for the valence bond theory in quantum chemistry) is a popular method in coordination chemistry to estimate the oxidation states of atoms. It is derived from the bond valence model, which is a simple yet robust model for validating chemical structures with ...
In quantum mechanics, a sum rule is a formula for transitions between energy levels, in which the sum of the transition strengths is expressed in a simple form. Sum rules are used to describe the properties of many physical systems, including solids, atoms, atomic nuclei, and nuclear constituents such as protons and neutrons.