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The pressure on a pressure-temperature diagram (such as the water phase diagram shown above) is the partial pressure of the substance in question. A phase diagram in physical chemistry, engineering, mineralogy, and materials science is a type of chart used to show conditions (pressure, temperature, etc.) at which thermodynamically distinct ...
The figure shows the schematic P-T diagram of a pure substance (as opposed to mixtures, which have additional state variables and richer phase diagrams, discussed below). The commonly known phases solid , liquid and vapor are separated by phase boundaries, i.e. pressure–temperature combinations where two phases can coexist.
A typical phase diagram.The solid green line applies to most substances; the dashed green line gives the anomalous behavior of water. In thermodynamics, the triple point of a substance is the temperature and pressure at which the three phases (gas, liquid, and solid) of that substance coexist in thermodynamic equilibrium. [1]
An unusual feature of the water phase diagram is that the solid–liquid phase line (illustrated by the dotted green line) has a negative slope. For most substances, the slope is positive as exemplified by the dark green line. This unusual feature of water is related to ice having a lower density than liquid water.
The amount of substance that transforms is a function of the amount of heat added. After the transition is complete, adding more heat increases the temperature. In other words, the enthalpy of a substance changes isothermally as it undergoes a physical change. The enthalpy change resulting from a phase transition is designated ΔH. There are ...
Phase transitions commonly refer to when a substance transforms between one of the four states of matter to another. At the phase transition point for a substance, for instance the boiling point, the two phases involved - liquid and vapor, have identical free energies and therefore are equally likely to exist. Below the boiling point, the ...
In thermodynamics, the phase rule is a general principle governing multi-component, multi-phase systems in thermodynamic equilibrium.For a system without chemical reactions, it relates the number of freely varying intensive properties (F) to the number of components (C), the number of phases (P), and number of ways of performing work on the system (N): [1] [2] [3]: 123–125
The phase diagram in the above diagram displays an alloy of two metals which forms a solid solution at all relative concentrations of the two species. In this case, the pure phase of each element is of the same crystal structure, and the similar properties of the two elements allow for unbiased substitution through the full range of relative ...