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A number of materials contract on heating within certain temperature ranges; this is usually called negative thermal expansion, rather than "thermal contraction".For example, the coefficient of thermal expansion of water drops to zero as it is cooled to 3.983 °C (39.169 °F) and then becomes negative below this temperature; this means that water has a maximum density at this temperature, and ...
To distinguish these two thermal expansion equations of state, the latter one is called pressure-dependent thermal expansion equation of state. To deveop the pressure-dependent thermal expansion equation of state, in an compression process at room temperature from (V 0, T 0, P 0) to (V 1, T 0,P 1), a general form of volume is expressed as
The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): = = Here is the thermal expansion coefficient: = is the isothermal compressibility (the inverse of the bulk modulus):
β is the thermal expansion coefficient (equals to 1/T, for ideal gases, where T is absolute temperature). is the kinematic viscosity; α is the thermal diffusivity; T s is the surface temperature; T ∞ is the quiescent temperature (fluid temperature far from the surface of the object) Gr x is the Grashof number for characteristic length x
If we bring it into thermal contact with the system whose temperature we wish to measure, wait until it equilibrates, and then measure the volume of the thermometer, we will be able to calculate the temperature of the system in question via T = PV/Nk. Hopefully, the thermometer will be small enough that it does not appreciably alter the ...
This concept lies in the basis for the kinetic theory of matter and thermal expansion of matter, which states as the temperature of a substance rises, so does the average kinetic energy of its molecules. As such, a rise in kinetic energy requires more space between the particles of a given substance, which leads to its physical expansion. [2]
Material will expand or contract depending on the material's thermal expansion coefficient. As long as the material is free to move, the material can expand or contract freely without generating stresses. Once this material is attached to a rigid body at multiple locations, thermal stresses can be created in the geometrically constrained region.
Increased thermal vibrations produce thermal expansion characterized by the coefficient of thermal expansion (CTE) that is the gradient of the graph of dimensional change versus temperature. CTE depends upon thermal transitions such as the glass transition. CTE of the glassy state is low, while at the glass transition temperature (Tg) increased ...