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Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO 2, commonly found in nature as quartz. [5] [6] In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and abundant families of materials, existing as a compound of several minerals and as a
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/100 ml), unless shown otherwise. The substances are listed in alphabetical order.
Colloidal silica gel with light opalescence. Silica gel is an amorphous and porous form of silicon dioxide (silica), consisting of an irregular tridimensional framework of alternating silicon and oxygen atoms with nanometer-scale voids and pores. The voids may contain water or some other liquids, or may be filled by gas or vacuum.
Like other chlorosilanes or silanes, silicon tetrachloride reacts readily with water: . SiCl 4 + 2 H 2 O → SiO 2 + 4 HCl. The reaction can be noticed on exposure of the liquid to air, as SiCl 4 vapour produces fumes as it reacts with moisture to give a cloud-like aerosol of silica and hydrochloric acid. [6]
W-silica is an unstable low-density form involving SiO tetrahedra sharing opposite edges instead of corners, forming parallel chains similarly to silicon disulfide (SiS 2) and silicon diselenide (SiSe 2): it quickly returns to forming amorphous silica with heat or traces of water. [14] Condensed polysilicic acid. Silica is rather inert chemically.
[4] [5] [6] Dehydrating the latter yields a hard translucent form of silica with atomic-scale pores, called silica gel, which is widely used as water absorbent and drying agent. Silica dissolves very sparingly in water [citation needed] and is present in seawater at concentrations below 100 parts per million. In such dilute solutions, silica is ...
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
When treated with calcium oxides and water, silicate minerals form Portland cement. Equilibria involving hydrolysis of silicate minerals are difficult to study. The chief challenge is the very low solubility of SiO 4 4-and its various protonated forms. Such equilibria are relevant to the processes occurring on geological time scales.