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Steam distillation is a means of purifying fatty acids, e.g. from tall oils. [9] Steam distillation is sometimes used in the chemical laboratory. Illustrative is a classic preparation of bromobiphenyl where steam distillation is used to first remove the excess benzene and subsequently to purifiy the brominated product. [10]
The Lindemann criterion states that melting occurs because of "vibrational instability", e.g. crystals melt; when the average amplitude of thermal vibrations of atoms is relatively high compared with interatomic distances, e.g. <δu 2 > 1/2 > δ L R s, where δu is the atomic displacement, the Lindemann parameter δ L ≈ 0.20...0.25 and R s is ...
For pure elements or compounds, e.g. pure copper, pure water, etc. the liquidus and solidus are at the same temperature, and the term melting point may be used.. There are also some mixtures which melt at a particular temperature, known as congruent melting.
Melting points (in blue) and boiling points (in pink) of the first eight carboxylic acids (°C). For most substances, melting and freezing points are approximately equal. For example, the melting and freezing points of mercury is 234.32 kelvins (−38.83 °C; −37.89 °F). [2]
Also acid ionization constant or acidity constant. A quantitative measure of the strength of an acid in solution expressed as an equilibrium constant for a chemical dissociation reaction in the context of acid-base reactions. It is often given as its base-10 cologarithm, p K a. acid–base extraction A chemical reaction in which chemical species are separated from other acids and bases. acid ...
Most liquids freeze by crystallization, formation of crystalline solid from the uniform liquid. This is a first-order thermodynamic phase transition, which means that as long as solid and liquid coexist, the temperature of the whole system remains very nearly equal to the melting point due to the slow removal of heat when in contact with air, which is a poor heat conductor.
For froth flotation, an aqueous slurry of the ground ore is treated with the frothing agent. An example is sodium ethyl xanthate as a collector in the flotation of galena (lead sulfide) to separate it from sphalerite (zinc sulfide). The polar part of xanthate anion attaches to the ore particles and the non-polar hydrocarbon part forms a ...
The dissociation of salts by solvation in a solution, such as water, means the separation of the anions and cations. The salt can be recovered by evaporation of the solvent. An electrolyte refers to a substance that contains free ions and can be used as an electrically conductive medium. Most of the solute does not dissociate in a weak ...