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The Baeyer–Villiger oxidation is an organic reaction that forms an ester from a ketone or a lactone from a cyclic ketone, using peroxyacids or peroxides as the oxidant. [1] The reaction is named after Adolf von Baeyer and Victor Villiger who first reported the reaction in 1899.
General formulas of an organic peroxy acid (top) compared with a carboxylic acid (bottom).. A peroxy acid (often spelled as one word, peroxyacid, and sometimes called peracid) is an acid which contains an acidic −OOH group.
Peroxyacetic acid, a peroxycarboxylic acid (formula: (RCO 3 H), is a reagent in organic synthesis. Prostaglandin G2 , an endo peroxide, the precursor to other prostaglandins One gap in the classes of organic peroxides is diphenyl peroxide.
meta-Chloroperoxybenzoic acid (mCPBA or mCPBA) is a peroxycarboxylic acid.It is a white solid often used widely as an oxidant in organic synthesis. mCPBA is often preferred to other peroxy acids because of its relative ease of handling.
Structure of the acryloyl group. α,β-Unsaturated carbonyl compounds featuring a carbonyl conjugated to an alkene that is terminal, or vinylic, contain the acryloyl group (H 2 C=CH−C(=O)−); it is the acyl group derived from acrylic acid.
The mechanism of carbonyl oxidation by iodine(III) reagents varies as a function of substrate structure and reaction conditions, but some generalizations are possible. Under basic conditions, the active iodinating species are iodine(III) compounds in which any relatively acidic ligands on iodine (such as acetate) have been replaced by alkoxide. [1]
Examples of orthoesters include the reagents trimethyl orthoformate and triethylorthoacetate. Another example is the bicyclic OBO protecting group (4-methyl-2,6,7-trioxa-bicyclo[2.2.2]octan-1-yl) which is formed by the action of (3-methyloxetan-3-yl)methanol on activated carboxylic acids in the presence of Lewis acids. The group is base stable ...
The Sarett oxidation is an organic reaction that oxidizes primary and secondary alcohols to aldehydes and ketones, respectively, using chromium trioxide and pyridine.Unlike the similar Jones oxidation, the Sarett oxidation will not further oxidize primary alcohols to their carboxylic acid form, neither will it affect carbon-carbon double bonds. [1]
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