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  2. Order statistic - Wikipedia

    en.wikipedia.org/wiki/Order_statistic

    The first order statistic (or ... (i.e. with rate parameter 1). This result was first published by ... the median is the one delimited by the 2nd and 5th order ...

  3. Rate equation - Wikipedia

    en.wikipedia.org/wiki/Rate_equation

    For a typical second-order reaction with rate equation = [] [], if the concentration of reactant B is constant then = [] [] = ′ [], where the pseudo–first-order rate constant ′ = []. The second-order rate equation has been reduced to a pseudo–first-order rate equation, which makes the treatment to obtain an integrated rate equation much ...

  4. Rate-determining step - Wikipedia

    en.wikipedia.org/wiki/Rate-determining_step

    In fact, however, the observed reaction rate is second-order in NO 2 and zero-order in CO, [5] with rate equation r = k[NO 2] 2. This suggests that the rate is determined by a step in which two NO 2 molecules react, with the CO molecule entering at another, faster, step. A possible mechanism in two elementary steps that explains the rate ...

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  6. Order of approximation - Wikipedia

    en.wikipedia.org/wiki/Order_of_approximation

    First-order approximation is the term scientists use for a slightly better answer. [3] Some simplifying assumptions are made, and when a number is needed, an answer with only one significant figure is often given ("the town has 4 × 10 3, or four thousand, residents"). In the case of a first-order approximation, at least one number given is exact.

  7. List of Runge–Kutta methods - Wikipedia

    en.wikipedia.org/wiki/List_of_Runge–Kutta_methods

    Two-stage 2nd order Diagonally Implicit Runge–Kutta method: x x 0 1 1 − x x 1 − x x {\displaystyle {\begin{array}{c|cc}x&x&0\\1&1-x&x\\\hline &1-x&x\\\end{array}}} Again, this Diagonally Implicit Runge–Kutta method is A-stable if and only if x ≥ 1 4 {\textstyle x\geq {\frac {1}{4}}} .

  8. First-order second-moment method - Wikipedia

    en.wikipedia.org/wiki/First-order_second-moment...

    For the second-order approximations of the third central moment as well as for the derivation of all higher-order approximations see Appendix D of Ref. [3] Taking into account the quadratic terms of the Taylor series and the third moments of the input variables is referred to as second-order third-moment method. [4]

  9. Stochastic dominance - Wikipedia

    en.wikipedia.org/wiki/Stochastic_dominance

    Stochastic dominance is a partial order between random variables. [1] [2] It is a form of stochastic ordering.The concept arises in decision theory and decision analysis in situations where one gamble (a probability distribution over possible outcomes, also known as prospects) can be ranked as superior to another gamble for a broad class of decision-makers.