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This substance is commonly called "commercial ammonium fluoride". The word "neutral" is sometimes added to "ammonium fluoride" to represent the neutral salt [NH 4]F as opposed to the "acid salt" (NH 4 HF 2). The acid salt is usually used in preference to the neutral salt in the etching of glass and related silicates. This property is shared ...
Chemical formula Synonyms CAS number C 10 H 16 N 2 O 8: Ethylenediaminetetraacetic acid (EDTA): 6381–92–6 C 12 H 22 O 11: sucrose: 57–50–1 C 18 H 29 O 3 S: sodium dodecyl benzenesulfonate: 2155–30–0
Ammonium bifluoride, as its name indicates, contains an ammonium cation ([NH 4] +), and a bifluoride (or hydrogen difluoride) anion ([HF 2] −).The triatomic bifluoride anion features a strong three-center four-electron bond (specifically, a symmetrical hydrogen bond) with a bond energy greater than 155 kJ/mol, [2] and an H-F length of 114 pm. [3]
Most other soluble salts of fluoride are in fact bifluorides, HF 2 –. Historically, there have been two main approaches to prepare tetramethylammonium fluoride: hydrofluoric acid neutralization of tetramethylammonium hydroxide, and salt metathesis between different ammonium salts and inorganic fluoride sources, such as KF or CsF. [1]
Buffered oxide etch is commonly used for more controllable etching. [1] Buffering HF with NH 4 F results in a solution with a more stable pH; thus, more stable concentrations of HF and HF − 2, and a more stable etch rate. [2] Some oxides produce insoluble products in HF solutions.
Tetra-n-butylammonium fluoride, commonly abbreviated to TBAF and n-Bu 4 NF, is a quaternary ammonium salt with the chemical formula (CH 3 CH 2 CH 2 CH 2) 4 N + F −. It is commercially available as the white solid trihydrate and as a solution in tetrahydrofuran. TBAF is used as a source of fluoride ion in organic solvents. [1]
Ammonium fluorosilicate (also known as ammonium hexafluorosilicate, ammonium fluosilicate or ammonium silicofluoride) has the formula (NH 4) 2 SiF 6. It is a toxic chemical, like all salts of fluorosilicic acid. [4] It is made of white crystals, [5] which have at least three polymorphs [6] and appears in nature as rare minerals cryptohalite or ...
Benzyltrimethylammonium fluoride is a quaternary ammonium salt. It is commercially available as the hydrate. The compound is a source of organic-soluble fluoride to removal of silyl ether protecting groups. As is the case for tetra-n-butylammonium fluoride and most other quaternary ammonium fluorides, the compound cannot be obtained in ...