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Printable version; Page information; Get shortened URL ... Di-tert-butyl ether chemical structure: Date: 22 April 2007: Source: ... Add a one-line explanation of what ...
Print/export Download as PDF; Printable version; In other projects Wikimedia Commons; Wikidata item; Appearance. ... Di-tert-butyl ether is a tertiary ether, ...
The numerical multiplier (or multiplying affix) in IUPAC nomenclature indicates how many particular atoms or functional groups are attached at a particular point in a molecule. The affixes are derived from both Latin and Greek .
The effect of the tert-butyl group on the progress of a chemical reaction is called the Thorpe–Ingold effect illustrated in the Diels-Alder reaction below. Compared to a hydrogen substituent, the tert-butyl substituent accelerates the reaction rate by a factor of 240. [2] tert-Butyl effect. The tert-butyl effect is an example of steric hindrance.
Each HHB of the tert-butyl network were calculated (in absence of steric repulsion) to contribute 0.7 kcal/mol of stabilization. Calculations with one of the tert-butyl substituents with a methyl, ethyl, or isopropyl group result in net repulsion due to the loss of HHBs. [26] In total, this forms the basis of the corset effect. [5]
Gasoline additives methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE), respectively, are produced by reacting methanol or ethanol with isobutylene contained in butene streams from olefin steam crackers or refineries, or with isobutylene from dehydrated TBA. Isobutylene is not isolated from the olefin or refinery butene stream ...
tert-Butyl alcohol (tert-Butanol, 2-methylpropanol) Ethers: Diethyl ether (ethoxyethane) Methyl propyl ether (methoxypropane, 1-methoxypropane) Methyl isopropyl ether or isopropyl methyl ether (2-methoxypropane)
Dibutyl ether is a chemical compound belonging to the ether family with the molecular formula of C 8 H 18 O. It is colorless, volatile, and flammable liquid and has peculiar ethereal smell. Liquid dibutyl ether is lighter than water. On the other hand, the vapor is heavier than air.
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