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For example, in the case of a simple gas of N particles with total energy U contained in a cube of volume V, in which a sample of the gas cannot be distinguished from any other sample by experimental means, a microstate will consist of the above-mentioned N! points in phase space, and the set of microstates will be constrained to have all ...
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Boltzmann's equation—carved on his gravestone. [1]In statistical mechanics, Boltzmann's equation (also known as the Boltzmann–Planck equation) is a probability equation relating the entropy, also written as , of an ideal gas to the multiplicity (commonly denoted as or ), the number of real microstates corresponding to the gas's macrostate:
A microstate of the system is a description of the positions and momenta of all its particles. The large number of particles of the gas provides an infinite number of possible microstates for the sample, but collectively they exhibit a well-defined average of configuration, which is exhibited as the macrostate of the system, to which each ...
There may easily be more than one microstate with the same macrostate. For example, for a fixed temperature, the system could have many dynamic configurations at the microscopic level. When used in this sense, a phase is a region of phase space where the system in question is in, for example, the liquid phase, or solid phase, etc.
Boltzmann's distribution is an exponential distribution. Boltzmann factor (vertical axis) as a function of temperature T for several energy differences ε i − ε j.. In statistical mechanics and mathematics, a Boltzmann distribution (also called Gibbs distribution [1]) is a probability distribution or probability measure that gives the probability that a system will be in a certain ...
The change in entropy in the entropy of mixing example may be viewed as an example of a non-extensive entropy resulting from the distinguishability of the two types of particles being mixed. Quantum particles are either bosons (following Bose–Einstein statistics ) or fermions (subject to the Pauli exclusion principle , following instead Fermi ...