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Barium carbonate is the inorganic compound with the formula BaCO 3. Like most alkaline earth metal carbonates, it is a white salt that is poorly soluble in water. It occurs as the mineral known as witherite. In a commercial sense, it is one of the most important barium compounds. [5]
Barium carbonate – BaCO 3 [85] Barium chlorate – Ba(ClO 3) 2 ... Water - H 2 O [204] He ... oxide – As 2 O 5; Barium oxide – BaO; Beryllium oxide – BeO;
The tables below provides information on the variation of solubility of different substances (mostly inorganic compounds) in water with temperature, at one atmosphere pressure. Units of solubility are given in grams of substance per 100 millilitres of water (g/(100 mL)), unless shown otherwise.
The following chart shows the solubility of various ionic compounds in water at 1 atm pressure and room temperature (approx. 25 °C, 298.15 K). "Soluble" means the ionic compound doesn't precipitate, while "slightly soluble" and "insoluble" mean that a solid will precipitate; "slightly soluble" compounds like calcium sulfate may require heat to precipitate.
The standard Gibbs free energy of formation (G f °) of a compound is the change of Gibbs free energy that accompanies the formation of 1 mole of a substance in its standard state from its constituent elements in their standard states (the most stable form of the element at 1 bar of pressure and the specified temperature, usually 298.15 K or 25 °C).
Solid Al 2 O 3: −1675.5 Aluminium hydroxide: Solid Al(OH) 3: −1277 Aluminium sulphate: Solid Al 2 (SO 4) 3: −3440 Barium chloride: Solid BaCl 2: −858.6 Barium carbonate: Solid BaCO 3: −1216 Barium hydroxide: Solid Ba(OH) 2: −944.7 Barium oxide: Solid BaO −548.1 Barium sulfate: Solid BaSO 4: −1473.3 Beryllium: Solid Be 0 ...
Barium carbonate is often added to maintain anhydrous and acid-free conditions. In the above reaction, while a mixture of isomeric allylic bromide products are possible, only one is created due to the greater stability of the 4-position radical over the methyl-centered radical.
Other compounds of barium find only niche applications, limited by the toxicity of Ba 2+ ions (barium carbonate is a rat poison), which is not a problem for the insoluble BaSO 4. Barium oxide coating on the electrodes of fluorescent lamps facilitates the release of electrons .