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Iridium acetylacetonate is the iridium coordination complex with the formula Ir(O 2 C 5 H 7) 3, which is sometimes known as Ir(acac) 3. The molecule has D 3 -symmetry. [ 2 ] It is a yellow-orange solid that is soluble in organic solvents.
Applications include their use as NMR "shift reagents" and as catalysts for organic synthesis, and precursors to industrial hydroformylation catalysts. C 5 H 7 O − 2 in some cases also binds to metals through the central carbon atom; this bonding mode is more common for the third-row transition metals such as platinum(II) and iridium(III).
Indium acetate is an acetate of indium, with the chemical formula In(CH 3 COO) 3. It is soluble in water, acetic acid and mineral acids. [ 1 ] It is the precursor of indium-containing compounds such as the solar cell materials CuInS 2 [ 2 ] and indium phosphide quantum dots .
Ruthenium(III) acetate, commonly known as basic ruthenium acetate, [1] describes a family of salts where the cation has the formula [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3] +.A representative derivative is the dihydrate of the tetrafluoroborate salt [Ru 3 O(O 2 CCH 3) 6 (OH 2) 3]BF 4 (H 2 O) 2, which is the source of the data in the table above. [2]
3 in hydrochloric acid, is often used as a starting material for the synthesis of other Ir(III) compounds. [2] Another compound used as a starting material is ammonium hexachloroiridate(III), (NH 4) 3 IrCl 6. In the presence of air, iridium metal dissolves in molten alkali-metal cyanides to produce the Ir(CN) 3− 6 (hexacyanoiridate) ion.
structure of the cation called basic iron acetate as determined from X-ray crystallography [4] Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts. It is slowly soluble in water and poorly soluble in acetic acid. [5] A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free ...
Lanthanum acetate is an inorganic compound, a salt of lanthanum with acetic acid with the chemical formula La(CH 3 CO 2) 3. According to X-ray crystallography, anhydrous lanthanum acetate is a coordination polymer. Each La(III) center is nine-coordinate, with two bidentate acetate ligands and the remaining sites occupied by oxygens provided by ...
Vaska's complex is the trivial name for the chemical compound trans-carbonylchlorobis(triphenylphosphine)iridium(I), which has the formula IrCl(CO)[P(C 6 H 5) 3] 2.This square planar diamagnetic organometallic complex consists of a central iridium atom bound to two mutually trans triphenylphosphine ligands, carbon monoxide and a chloride ion.
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