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Polybutylene terephthalate (PBT) is a thermoplastic engineering polymer that is used as an insulator in the electrical and electronics industries. [2] It is a thermoplastic (semi-)crystalline polymer , and a type of polyester .
Since the polymerization happens in the crystalline lattice without the aid of solvents or reagents, it comes under the domain of green chemistry. [18] Also, the topochemical polymerizations are mostly atom economical reactions. The product can be obtained without any further purifications.
RAFT polymerization has been used to synthesize a wide range of polymers with controlled molecular weight and low polydispersities (between 1.05 and 1.4 for many monomers). RAFT polymerization is known for its compatibility with a wide range of monomers as compared to other controlled radical polymerizations.
In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. [1] [2] [3] There are many forms of polymerization [4] and different systems exist to categorize them. IUPAC definition for ...
Isotactic PB-1 is produced commercially using two types of heterogeneous Ziegler–Natta catalysts. [3] The first type of catalyst contains two components, a solid pre-catalyst, the δ-crystalline form of TiCl 3, and solution of an organoaluminum cocatalyst, such as Al(C 2 H 5) 3.
Complex architecture polymers can be synthesized either with the use of specially tailored starting compounds or by first synthesising linear chains which undergo further reactions to become connected together. Knotted polymers consist of multiple intramolecular cyclization units within a single polymer chain.
A polymer field theory is a statistical field theory describing the statistical behavior of a neutral or charged polymer system. It can be derived by transforming the partition function from its standard many-dimensional integral representation over the particle degrees of freedom in a functional integral representation over an auxiliary field function, using either the Hubbard–Stratonovich ...
There are many properties of polymeric materials that influence their mechanical properties. As the degree of polymerization goes up, so does the polymer’s strength, as a longer chains have high Van der Waals interactions and chain entanglement. Long polymers can entangle, which leads to a subsequent increase in bulk modulus. [11]