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A supercritical fluid (SCF) is a substance at a temperature and pressure above its critical point, where distinct liquid and gas phases do not exist, but below the pressure required to compress it into a solid. [1]
It is called supercritical fluid. The common textbook knowledge that all distinction between liquid and vapor disappears beyond the critical point has been challenged by Fisher and Widom , [ 8 ] who identified a p – T line that separates states with different asymptotic statistical properties ( Fisher–Widom line ).
Supercritical carbon dioxide can be used as a solvent in dry cleaning. [4] Supercritical carbon dioxide is used as the extraction solvent for creation of essential oils and other herbal distillates. [5] Its main advantages over solvents such as hexane and acetone in this process are that it is non-flammable and does not leave toxic residue.
Supercritical drying, a process used to remove liquid in a precisely controlled way, similar to freeze drying; Supercritical fluid, a substance at a temperature and pressure above its thermodynamic critical point: Supercritical carbon dioxide:
A supercritical flow is a flow whose velocity is larger than the wave velocity. [clarification needed] The analogous condition in gas dynamics is supersonic speed.According to the website Civil Engineering Terms, supercritical flow is defined as follows: The flow at which depth of the channel is less than critical depth, velocity of flow is greater than critical velocity and slope of the ...
This fundamental law determines the different adsorption mechanism for the subcritical and supercritical regions. For the subcritical region, the highest equilibrium pressure of adsorption is the saturation pressure of adsorbate. Beyond condensation happens. Adsorbate in the adsorbed phase is largely in liquid state, based on which different ...
The critical point is 21.7 MPa at a temperature of 374 °C, above which water is supercritical rather than superheated. Above about 300 °C, water starts to behave as a near-critical liquid, and physical properties such as density start to change more significantly with pressure.
However, different criteria still allow to distinguish liquid-like and more gas-like states of a supercritical fluid. These criteria result in different boundaries in the pT plane. These lines emanate either from the critical point, or from the liquid–vapor boundary (boiling curve) somewhat below the critical point.