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An ester of a carboxylic acid.R stands for any group (typically hydrogen or organyl) and R ′ stands for any organyl group.. In chemistry, an ester is a compound derived from an acid (organic or inorganic) in which the hydrogen atom (H) of at least one acidic hydroxyl group (−OH) of that acid is replaced by an organyl group (R ′). [1]
A general acyl group (blue) in a ketone (top left), as an acylium cation (top centre), as an acyl radical (top right), an aldehyde (bottom left), ester (bottom centre) or amide (bottom right). ( R 1 , R 2 and R 3 stands for organyl substituent or hydrogen in the case of R 1 )
The Yamaguchi esterification is the chemical reaction of an aliphatic carboxylic acid and 2,4,6-trichlorobenzoyl chloride (TCBC, Yamaguchi reagent) to form a mixed anhydride which, upon reaction with an alcohol in the presence of stoichiometric amount of DMAP, produces the desired ester. It was first reported by Masaru Yamaguchi et al. in 1979 ...
Phenyl acetate is the ester of phenol and acetic acid.It can be produced by reacting phenol with acetic anhydride or acetyl chloride.. Phenyl acetate can be separated into phenol and an acetate salt, via saponification: heating the phenyl acetate with a strong base, such as sodium hydroxide, will produce phenol and an acetate salt (sodium acetate, if sodium hydroxide were used).
A common type of organic acid anhydride is a carboxylic anhydride, where the parent acid is a carboxylic acid, the formula of the anhydride being (RC(O)) 2 O. Symmetrical acid anhydrides of this type are named by replacing the word acid in the name of the parent carboxylic acid by the word anhydride. [2] Thus, (CH 3 CO) 2 O is called acetic ...
They are analogous to carboxylate esters (R−C(=O)−O−R’) with the sulfur in the thioester replacing oxygen in the carboxylate ester, as implied by the thio-prefix. They are the product of esterification of a carboxylic acid (R−C(=O)−O−H) with a thiol (R'−S−H).
DIBP is synthesized by reaction of phthalic anhydride with isobutanol. Various acids are used as a catalyst, such as sulfuric acid, sulfonated graphene, or iron(III) chloride. Water is a byproduct. Using sulfuric acid, the yield is 61% yield. [6] Sulfuric acid catalyzed reaction of isobutanol and phthalic anhydride to form diisobutyl phthalate
In terms of their mode of action, the anhydride is proposed to react with the hydroxyl groups on the cellulose, forming an ester. The alkenyl side-chain modifies the surface properties of the paper product. [2] The application is similar to that for alkyl ketene dimers. In the United States alkenylsuccinic anhydrides are the preferred paper ...