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Chromium trioxide (also known as chromium(VI) oxide or chromic anhydride) is an inorganic compound with the formula CrO 3. It is the acidic anhydride of chromic acid, and is sometimes marketed under the same name. [6] This compound is a dark-purple solid under anhydrous conditions and bright orange when wet. The substance dissolves in water ...
3 has the corundum structure, consisting of a hexagonal close packed array of oxide anions with 2 ⁄ 3 of the octahedral holes occupied by chromium. Similar to corundum, Cr 2 O 3 is a hard, brittle material (Mohs hardness 8 to 8.5). [4] It is antiferromagnetic up to 307 K, the Néel temperature.
Chromium oxide may refer to: Chromium(II) oxide, CrO; Chromium(III) oxide, Cr 2 O 3; Chromium dioxide (chromium(IV) oxide), CrO 2, which includes the hypothetical compound chromium(II) chromate; Chromium trioxide (chromium(VI) oxide), CrO 3; Chromium(VI) oxide peroxide, CrO 5; Mixed valence species, such as Cr 8 O 21
A trioxide is a compound with three oxygen atoms. For metals with the M 2 O 3 formula there are several common structures. Al 2 O 3 , Cr 2 O 3 , Fe 2 O 3 , and V 2 O 3 adopt the corundum structure .
Chromium compounds are compounds containing the element chromium (Cr). Chromium is a member of group 6 of the transition metals. The +3 and +6 states occur most commonly within chromium compounds, followed by +2; charges of +1, +4 and +5 for chromium are rare, but do nevertheless occasionally exist. [3] [4]
A large number of chromium(III) compounds are known, such as chromium(III) nitrate, chromium(III) acetate, and chromium(III) oxide. [33] Chromium(III) can be obtained by dissolving elemental chromium in acids like hydrochloric acid or sulfuric acid, but it can also be formed through the reduction of chromium(VI) by cytochrome c7. [34] The Cr 3+
The complex is produced by treating chromium trioxide with pyridine. [2] The complex is diamagnetic. According to X-ray crystallography, the complex is 5-coordinate with mutually trans pyridine ligands. The Cr-O and Cr-N distances are respectively 163 and 215 picometers. [3] In terms of history, the complex was first produced by Sisler et al. [4]
Chromium(II) oxide (CrO) is an inorganic compound composed of chromium and oxygen. [1] It is a black powder that crystallises in the rock salt structure. [2] Hypophosphites may reduce chromium(III) oxide to chromium(II) oxide: H 3 PO 2 + 2 Cr 2 O 3 → 4 CrO + H 3 PO 4. It is readily oxidized by the atmosphere. CrO is basic, while CrO 3 is ...